Alkyne‐based click polymerizations have been nurtured into a powerful synthetic technique
for the preparation of new polymers with advanced structures and versatile properties …

This comprehensive review aims to provide an in‐depth analysis of the catalytic
performance of 1, 5, 7‐triazabicyclo [4, 4, 0] dec‐5‐ene (TBD) in polymer synthesis. TBD, a …

TBD (1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene) is an organic superbase with unique catalytic
effects due to its bifunctionality. It is already successfully used as a versatile catalyst, eg, for …

In this work, a novel, straightforward, robust, fast, and organocatalyst-mediated phospha-
Michael reaction (OCPMR) was developed for the addition of phosphorus nucleophiles to …

The use of metal-free click reactions for the design and synthesis of novel flame retardant
reactive monomers for thiol-ene photopolymerization is an intriguing area of research. In this …

An organocatalyst-mediated, extremely rapid, robust, and practical poly (disulfide) synthesis
method is introduced to polymer chemistry. A variety of organocatalysts were initially …

The quest for sustainable monomers and “green” synthetic pathways for the design,
fabrication, and modification of various polymers is of great importance and attracts a great …

Within the toolbox of click chemistry, the utilization of thiol-ene reactions for polymer
synthesis and modification is a current area of intense attention. Thiol-ene click reactions are …

Herein, we prepare a polythioether with double “clickable” alkyne groups in each repeating
unit via an extremely rapid polymerization method and combine it with Cu (I)-catalyzed azide …

Novel poly (dithiophosphate) s (PDTPs) were successfully synthesized under mild
conditions without any additive in the presence of THF or toluene diluents at 60° C by a …