The importance of autocatalysis spans from practical applications such as in chemically
amplified photoresists, to autocatalysis playing a fundamental role in evolution as well as a …

Many enzymes utilize interactions extending beyond the primary coordination sphere to
enhance catalyst activity and/or selectivity. Such interactions could improve the efficacy of …

The dearomative cycloaddition reaction serves as a blueprint for creating sp3-rich three-
dimensional molecular topology from flat-aromatic compounds. However, severe reactivity …

Regulating hydrogel actuators with chemical reaction networks is instrumental for
constructing life‐inspired smart materials. Herein, hydrogel actuators are engineered that …

This paper addresses the mechanism for rectification in molecular tunneling junctions based
on alkanethiolates terminated by a bipyridine group complexed with a metal ion, that is …

The Cu-catalyzed azide–alkyne cycloaddition (CuAAC) reaction is used as a ligation tool
throughout chemical and biological sciences. Despite the pervasiveness of CuAAC, there is …

A series of Cu (II) complexes, 1–4 and 6, were synthesized through a reaction of amine-
functionalized pincer-like ligands, HL 1, 2, L a, b, and a bidentate ligand L 1 with CuCl2 …

A recent experimental study reported a visible-light-mediated aerobic oxidative coupling
reaction of phenol with alkynes that produces hydroxyl-functionalized aryl ketones using …

While the integration of supramolecular principles in catalysis attracts increasing attention, a
direct comparative assessment of the resulting systems catalysts to work out distinct …

Autocatalytic and oscillatory networks of organic reactions are important for designing life-
inspired materials and for better understanding the emergence of life on Earth; however, the …