Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

High-valent metal–oxo species with multiply-bonded M–O groups have been proposed as
key intermediates in many biological and abiological catalytic oxidation reactions. These …

Water has been recognized as an excellent solvent for maneuvering both the catalytic
activity and selectivity, especially in the case of heterogeneous catalysis. However …

Utilization of O2 as an abundant and environmentally benign oxidant is of great interest in
the design of bioinspired synthetic catalytic oxidation systems. Metalloenzymes activate O2 …

Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Conspectus Recent efforts to design synthetic iron catalysts for the selective and efficient
oxidation of C–H and C C bonds have been inspired by a versatile family of nonheme iron …

The selective functionalization of strong C− H bonds and the oxidation of water by cheap
and nontoxic metals are some of the key targets of chemical research today. It has been …

An unprecedentedly reactive iron species (2) has been generated by reaction of excess
peracetic acid with a mononuclear iron complex [FeII (CF3SO3) 2 (PyNMe3)](1) at cryogenic …

Catalysts for the oxidation of H2O are an integral component of solar energy to fuel
conversion technologies. Although catalysts based on scarce and precious metals have …

Iron is the most common metal by mass on earth and represents the basic element of
industrial society. The usage of iron to synthesize consumer products and to remediate …