Recent advances in subphthalocyanines and related subporphyrinoids

G Lavarda, J Labella, MV Martínez-Díaz… - Chemical Society …, 2022 - pubs.rsc.org
Half a century after the synthesis of the first subporphyrinoid, the study of tripyrrole and
trisoindole porphyrin analogues constitutes a fervent and rapidly expanding research area …

An exciting twenty-year journey exploring porphyrinoid-based photo-and electro-active systems

G Bottari, G de la Torre, DM Guldi, T Torres - Coordination Chemistry …, 2021 - Elsevier
This review highlights the combined effort of the Torres and Guldi groups in the preparation
and study of porphyrinoid-based photo-and electro-active systems. The perfect synergy …

Synthesis, characterization and unusual near-infrared luminescence of 1, 1, 4, 4-tetracyanobutadiene derivatives

AT Bui, C Philippe, M Beau, N Richy… - Chemical …, 2020 - pubs.rsc.org
Two 1, 1, 4, 4-tetracyanobutadiene (TCBD) derivatives were prepared by [2+ 2]
cycloaddition–retroelectrocyclization from ynamides bearing either a pyrene (1) or a …

Interfacing high‐energy charge‐transfer states to a near‐ir sensitizer for efficient electron transfer upon near‐ir irradiation

D Pinjari, AZ Alsaleh, Y Patil, R Misra… - Angewandte Chemie …, 2020 - Wiley Online Library
Push–pull systems comprising of triphenylamine–tetracyanobutadiene (TPA‐TCBD), a high‐
energy charge‐transfer species, are linked to a near‐IR sensitizer, azaBODIPY, for …

Tetracyanobutadiene Bridged Push‐Pull Chromophores: Development of New Generation Optoelectronic Materials

Y Patil, H Butenschön, R Misra - The Chemical Record, 2023 - Wiley Online Library
This review describes the design strategies used for the synthesis of various
tetracyanobutadiene bridged donor‐acceptor molecular architectures by a click type [2+ 2] …

Photoinduced Charge Separation Prompted Intervalence Charge Transfer in a Bis (thienyl) diketopyrrolopyrrole Bridged Donor‐TCBD Push‐Pull System

F Khan, Y Jang, Y Patil, R Misra… - Angewandte …, 2021 - Wiley Online Library
Intervalence charge transfer (IVCT), a phenomenon observed in molecular systems
comprised of two redox centers differing in oxidation states by one unit, is reported in a …

Charge stabilization via electron exchange: excited charge separation in symmetric, central triphenylamine derived, dimethylaminophenyl–tetracyanobutadiene donor …

IS Yadav, AZ Alsaleh, R Misra, F D'Souza - Chemical science, 2021 - pubs.rsc.org
Photoinduced charge separation in donor–acceptor conjugates plays a pivotal role in
technology breakthroughs, especially in the areas of efficient conversion of solar energy into …

Near‐IR Intramolecular Charge Transfer in Strongly Interacting Diphenothiazene‐TCBD and Diphenothiazene‐DCNQ Push‐Pull Triads

IS Yadav, Y Jang, Y Rout, MB Thomas… - … A European Journal, 2022 - Wiley Online Library
Three types of phenothiazines dimers (PTZ‐PTZ, 1–3), covalently linked with one or two
acetylene linkers, were synthesized by copper‐mediated Eglinton and Pd‐catalyzed …

Symmetrically Functionalized Copper and Silver Corrole‐Bis‐Tetracyanobutadiene Push‐Pull Conjugates: Efficient Population of Triplet States via Charge Transfer

I Yadav, JK Sharma, M Sankar… - Chemistry–A European …, 2023 - Wiley Online Library
Copper and silver tritolylcorroles (TTC) are symmetrically functionalized to carry two
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …

Excited‐state electron transfer in 1, 1, 4, 4‐Tetracyanobuta‐1, 3‐diene (TCBD)‐and cyclohexa‐2, 5‐diene‐1, 4‐diylidene‐expanded TCBD‐substituted BODIPY …

M Poddar, Y Jang, R Misra… - Chemistry–A European …, 2020 - Wiley Online Library
A new set of donor–acceptor (D–A) conjugates capable of undergoing ultrafast electron
transfer were synthesized using 4, 4‐difluoro‐4‐bora‐3a, 4a‐diaza‐s‐indacene (BODIPY) …