Beckmann rearrangement catalysis: A review of recent advances

K Kaur, S Srivastava - New Journal of Chemistry, 2020 - pubs.rsc.org
The Beckmann rearrangement, named after the German chemist Ernst Otto Beckmann
(1853–1923), is an acid catalyzed rearrangement of an oxime to an amide. The Beckmann …

An overview of caprolactam synthesis

R Kumar, S Shah, P Paramita Das… - Catalysis …, 2019 - Taylor & Francis
Caprolactam is the precursor of many industrial chemical productions as in nylon industry,
plastic industry, paint industry, lysine synthesis and cross-linking for polyurethanes. The …

Tailoring Zn-based diacidic functionalization of Deep eutectic solvent Catalyst: Green and efficient synthesis of ε-Caprolactam under mild conditions

S Sun, Y Li, R Sun, L Jiao, S Liu, S Yu - Fuel, 2024 - Elsevier
A novel Zn-based acidic functionalized deep eutectic solvent (DES) catalyst were prepared
by a “tailoring” mixing procedure of Brønsted acidic hydrogen bond donors (HBD) and Lewis …

High-yield and high-efficiency conversion of cyclohexanone oxime to ε-caprolactam in a green and facile reaction process over deep eutectic solvents

S Sun, S Liu, F Yu, J Zhang, W Xing, S Yu - Chemical Engineering Science, 2022 - Elsevier
Abstract ε-Caprolactam (CPL) is mainly produced through Beckmann rearrangement of
cyclohexanone oxime (CHO) catalyzed by oleum in industry, which suffers the problems …

Reusable deep eutectic solvents for clean ε-caprolactam synthesis under mild conditions

S Sun, S Liu, F Yu, J Zhang, W Xing… - … Sustainable Chemistry & …, 2022 - ACS Publications
A deep eutectic solvent (DES) with adjustable Brønsted acidity was prepared easily by
choline chloride (ChCl) and trifluoromethanesulfonic acid (TfOH). The obtained DES …

Toward the efficient synthesis of pseudoionone from citral in a continuous-flow microreactor

F Zhou, H Liu, Z Wen, B Zhang… - Industrial & Engineering …, 2018 - ACS Publications
Pseudoionone (PI) is a well-known and widely used precursor for ionones, which have been
substantially applied in flavor, fragrance and pharmaceutical industry. The phase behavior …

In situ functionalized sulfonic copolymer toward recyclable heterogeneous catalyst for efficient Beckmann rearrangement of cyclohexanone oxime

D Li, D Mao, J Li, Y Zhou, J Wang - Applied Catalysis A: General, 2016 - Elsevier
Exploring environmentally friendly, efficient and recyclable heterogeneous catalysts for low-
temperature liquid-phase organic reactions are important for the development of green and …

Comprehensive updates on Beckmann Rearrangement

J Kaushik, S Jain, P Malik, J Kumawat, P Jain… - …, 2024 - Wiley Online Library
Beckmann rearrangement has been quite successful in the preparation of many medicinally
potent scaffolds. In synthetic organic chemistry, the Beckmann rearrangement is quite …

Novel Brønsted Acidic Ionic Liquids as High Efficiency Catalysts for Liquid-Phase Beckmann Rearrangement

C Ren, Z Wang, Q Gao, J Li, S Jiang, Q Huang, Y Yang… - Catalysts, 2023 - mdpi.com
Exploring environmentally friendly, efficient, cheap and recyclable catalysts are essential for
the development of green, sustainable and mild processes for the liquid-phase Beckmann …

Organocatalyzed Beckmann rearrangement of cyclohexanone oxime in a microreactor: Kinetic model and product inhibition

C Du, J Zhang, G Luo - AIChE Journal, 2018 - Wiley Online Library
The kinetic study of Beckmann rearrangement of cyclohexanone oxime catalyzed by
trifluoroacetic acid and acetonitrile in a microreactor is presented in this article. Parametric …