Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …
coordination polymers (CPs) have garnered attention due to their modular nature and …
Metal-organic frameworks in Russia: From the synthesis and structure to functional properties and materials
MA Agafonov, EV Alexandrov, NA Artyukhova… - Journal of Structural …, 2022 - Springer
Current research fields of metal-organic frameworks (MOFs), which are being developed in
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …
The Versatility of Ethylene Glycol to Tune the Dimensionality and Magnetic Properties in DyIII-Anilato-Based Single-Ion Magnets
S Benmansour, C Pintado-Zaldo… - Crystal Growth & …, 2023 - ACS Publications
We exploit the high versatility of the solvent ethylene glycol (eg= CH2OH-CH2OH) acting as
a ligand with three different coordination modes: terminal (κ O), chelate (κ2 O, O′), and …
a ligand with three different coordination modes: terminal (κ O), chelate (κ2 O, O′), and …
Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal–organic framework
M Oggianu, F Bertolotti, F Manna, F Congiu… - Dalton …, 2024 - pubs.rsc.org
Novel heteroleptic anilate-based lanthanide MOFs (LnIII= Tb, Dy, Ho) have been obtained
under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally …
under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally …
Redox-active benzoquinones as challenging “non-innocent” linkers to construct 2D frameworks and nanostructures with tunable physical properties
N Monni, MS Angotzi, M Oggianu… - Journal of Materials …, 2022 - pubs.rsc.org
Exploiting redox activity in supramolecular frameworks such as coordination polymers, metal–
organic frameworks and related nanostructures is of paramount importance both at the …
organic frameworks and related nanostructures is of paramount importance both at the …
Redox activity as a powerful strategy to tune magnetic and/or conducting properties in benzoquinone-based metal-organic frameworks
N Monni, M Oggianu, S Ashoka Sahadevan… - Magnetochemistry, 2021 - mdpi.com
Multifunctional molecular materials have attracted material scientists for several years as
they are promising materials for the future generation of electronic devices. Careful selection …
they are promising materials for the future generation of electronic devices. Careful selection …
Combined experimental/theoretical study on the luminescent properties of homoleptic/heteroleptic erbium (III) anilate-based 2D coordination polymers
S Ashoka Sahadevan, F Manna, A Abhervé… - Inorganic …, 2021 - ACS Publications
The synthesis, structural and photophysical characterization, and theoretical studies on
homo/heteroleptic neutral 2D-layered coordination polymers (CPs), obtained by combining …
homo/heteroleptic neutral 2D-layered coordination polymers (CPs), obtained by combining …
Anilato‐Based Coordination Polymers with Slow Relaxation of the Magnetization: Role of the Synthetic Method and Anilato Ligand
S Benmansour, C Pintado‐Zaldo… - … A European Journal, 2024 - Wiley Online Library
We have prepared and characterized three coordination polymers formulated as [Dy2
(C6O4Cl2) 3 (fma) 6]⋅ 4.5 fma (1) and [Dy2 (C6O4X2) 3 (fma) 6]⋅ 4fma⋅ 2H2O with X= Br …
(C6O4Cl2) 3 (fma) 6]⋅ 4.5 fma (1) and [Dy2 (C6O4X2) 3 (fma) 6]⋅ 4fma⋅ 2H2O with X= Br …
Lanthanoid-anilato complexes and lattices
S Benmansour, CJ Gómez-García - Magnetochemistry, 2020 - mdpi.com
In this review, we describe all the structurally characterized complexes containing
lanthanoids (Ln, including La and group 3 metals: Y and Lu) and any anilato-type ligand (3 …
lanthanoids (Ln, including La and group 3 metals: Y and Lu) and any anilato-type ligand (3 …
Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks
S Benmansour, A Hernández-Paredes… - Chemical …, 2020 - pubs.rsc.org
A series of multifunctional 2D frameworks prepared with Dy (III) and the bromanilato ligand,
formulated as:[Dy2 (C6O4Br2) 3 (G) n]· nG with G= H2O, dimethylformamide (dmf) and …
formulated as:[Dy2 (C6O4Br2) 3 (G) n]· nG with G= H2O, dimethylformamide (dmf) and …