Enzyme-mediated oxidations for the chemist

F Hollmann, IWCE Arends, K Buehler, A Schallmey… - Green …, 2011 - pubs.rsc.org
Biocatalysis is an enabling technology adding to organic oxidation chemistry. Especially the
high selectivity of enzymatic oxidation coevally operating under mild conditions and not …

Immobilised enzymes in biorenewables production

MCR Franssen, P Steunenberg, EL Scott… - Chemical Society …, 2013 - pubs.rsc.org
Oils, fats, carbohydrates, lignin, and amino acids are all important raw materials for the
production of biorenewables. These compounds already play an important role in everyday …

Biocatalytic redox reactions for organic synthesis: nonconventional regeneration methods

F Hollmann, IWCE Arends, K Buehler - ChemCatChem, 2010 - Wiley Online Library
Redox enzymes have tremendous potential as catalysts for preparative organic chemistry.
Their usually high selectivity, paired with their catalytic efficiency under mild reaction …

Hydrogen peroxide in biocatalysis. A dangerous liaison

K Hernandez, A Berenguer-Murcia… - Current Organic …, 2012 - ingentaconnect.com
Hydrogen peroxide is a substrate or side-product in many enzyme-catalyzed reactions. For
example, it is a side-product of oxidases, resulting from the re-oxidation of FAD with …

Rational co‐immobilization of bi‐enzyme cascades on porous supports and their applications in bio‐redox reactions with in situ recycling of soluble cofactors

J Rocha‐Martín, B Rivas, R Muñoz, JM Guisán… - …, 2012 - Wiley Online Library
In bio‐redox cascade reactions that are immobilized on porous supports, mass‐transfer
limitations may impede the effective concentration of the cofactor around the corresponding …

The effect of dissolved oxygen on kinetics during continuous biocatalytic oxidations

RM Lindeque, JM Woodley - Organic Process Research & …, 2020 - ACS Publications
Conventional oxidation catalysts frequently exhibit limited selectivity, restricting their use in
industrial syntheses. In particular, for the continuous synthesis of complex active …

Recent advances in cofactor regeneration systems applied to biocatalyzed oxidative processes

C Rodriguez, I Lavandera, V Gotor - Current Organic Chemistry, 2012 - ingentaconnect.com
Nowadays, the design of sustainable processes applicable at industrial scale is highly
desirable due to environmental reasons. The use of biocatalytic reactions to carry out …

Oriented coimmobilization of oxidase and catalase on tailor-made ordered mesoporous silica

JM Bolivar, V Gascon, C Marquez-Alvarez, RM Blanco… - Langmuir, 2017 - ACS Publications
Mesoporous silica materials are promising carriers for enzyme immobilization in
heterogeneous biocatalysis applications. By tailoring their pore structural framework, these …

Threonine aldolase immobilization on different supports for engineering of productive, cost-efficient enzymatic microreactors

H Fu, I Dencic, J Tibhe, CAS Pedraza, Q Wang… - Chemical engineering …, 2012 - Elsevier
This paper consists of two parts–a detailed experimental investigation on the activity of
supported threonine aldolase for use in a microreactor/flow reactor and a generic …

Co-localization of oxidase and catalase inside a porous support to improve the elimination of hydrogen peroxide: Oxidation of biogenic amines by amino oxidase from …

P García-García, J Rocha-Martin… - Enzyme and microbial …, 2018 - Elsevier
Diamine oxidase (DAO) from Pisum sativum is an enzyme that catalyzes the degradation of
biogenic amines (BA) present in wine, producing harmless aldehydes and hydrogen …