How to Assess and Predict Electrical Double Layer Properties. Implications for Electrocatalysis

CM Schott, PM Schneider, KT Song, H Yu… - Chemical …, 2024 - ACS Publications
The electrical double layer (EDL) plays a central role in electrochemical energy systems,
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …

Exploration of the electrical double-layer structure: Influence of electrolyte components on the double-layer capacitance and potential of maximum entropy

RW Haid, X Ding, TK Sarpey, AS Bandarenka… - Current Opinion in …, 2022 - Elsevier
Understanding the electrical double-layer structure is of paramount importance for designing
efficient electrochemical energy conversion systems. Under this aspect, this short review …

Acidic Hydrogen Evolution Electrocatalysis at High‐Entropy Alloys Correlates with its Composition‐Dependent Potential of Zero Charge

M Kim, E Batsa Tetteh, OA Krysiak… - Angewandte Chemie …, 2023 - Wiley Online Library
The vast possibilities in the elemental combinations of high‐entropy alloys (HEAs) make it
essential to discover activity descriptors for establishing rational electrocatalyst design …

Cooperative Effect of Cations and Catalyst Structure in Tuning Alkaline Hydrogen Evolution on Pt Electrodes

A Goyal, S Louisia, P Moerland… - Journal of the American …, 2024 - ACS Publications
The kinetics of hydrogen evolution reaction (HER) in alkaline media, a reaction central to
alkaline water electrolyzers, is not accurately captured by traditional adsorption-based …

[HTML][HTML] pH dependence of noble metals dissolution: Platinum

V Briega-Martos, K Stojanovski, M Zlatar, C Göllner… - Electrochimica …, 2024 - Elsevier
Obtaining new information about the dissolution behavior of platinum in different pH
conditions can help understand the stability of this metal in a wide variety of electrochemical …

Harnessing Electrolyte Chemistry to Advance Oxygen Reduction Catalysis for Fuel Cells and Electrosynthesis

YY Zhao, W Yu, X Sun, H Huang, F Li, M Luo - ACS Catalysis, 2024 - ACS Publications
Oxygen reduction reaction (ORR) is ubiquitous in many important energy conversion
technologies, encompassing fuel cells, metal-air batteries, and H2O2 electrosynthesis …

Sensitivity Analysis of Electrochemical Double Layer Approximations on Electrokinetic Predictions: Case Study for CO Reduction on Copper

AJW Wong, B Tran, N Agrawal… - The Journal of …, 2024 - ACS Publications
Density functional theory (DFT) modeling has been useful to electrocatalyst research, yet
simulating the complexities of the electrode–electrolyte interface hinders progress in …

Understanding surface charge effects in electrocatalysis. Part 2: Hydrogen peroxide reactions at platinum

J Huang, V Climent, A Groß, JM Feliu - Chinese Journal of Catalysis, 2022 - Elsevier
Electrocatalytic activity is influenced by the surface charge on the solid catalyst.
Conventionally, our attention has been focused on how the surface charge shapes the …

Understanding electrochemical interfaces through comparing experimental and computational charge density–potential curves

N Mohandas, S Bawari, JJT Shibuya, S Ghosh… - Chemical …, 2024 - pubs.rsc.org
Electrode–electrolyte interfaces play a decisive role in electrochemical charge accumulation
and transfer processes. Theoretical modelling of these interfaces is critical to decipher the …

Solvent-mediated outer-sphere CO 2 electro-reduction mechanism over the Ag111 surface

V Sinha, E Khramenkova, EA Pidko - Chemical Science, 2022 - pubs.rsc.org
The electrocatalytic CO2 reduction reaction (CO2RR) is one of the key technologies of the
clean energy economy. Molecular-level understanding of the CO2RR process is …