[HTML][HTML] Design of lanthanide based metal–organic polyhedral cages for application in catalysis, sensing, separation and magnetism

DJ Bell, LS Natrajan, IA Riddell - Coordination Chemistry Reviews, 2022 - Elsevier
Lanthanide organic polyhedral cage complexes are a class of supramolecular compounds
that present exciting opportunities in applications ranging from sensing to catalysis and …

Self-assembly of triple-stranded lanthanide molecular quasi-lantern containing 2, 2′-bipyridine receptor: luminescence sensing and magnetic property

F Yin, Z Liu, J Yang, LP Zhou, CB Tian, QF Sun - ACS omega, 2023 - ACS Publications
Ln2 L 3-type supramolecular architectures have received significant attention recently due to
their unique magnetism and optical properties. Herein, we report the triple-stranded Ln2 L 3 …

Hexanuclear Ln6L6 Complex Formation by Using an Unsymmetric Ligand

DJ Bell, T Zhang, N Geue, CJ Rogers… - … A European Journal, 2023 - Wiley Online Library
Multinuclear, self‐assembled lanthanide complexes present clear opportunities as sensors
and imaging agents. Despite the widely acknowledged potential of this class of …

Ligand Chirality Transfer from Solution State to the Crystalline Self‐Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems

DF Caffrey, T Gorai, B Rawson… - Advanced …, 2024 - Wiley Online Library
The synthesis of a family of chiral and enantiomerically pure pyridyl‐diamide (pda) ligands
that upon complexation with europium [Eu (CF3SO3) 3] result in chiral complexes with metal …

Formation of lanthanide luminescent di-metallic helicates in solution using a bis-tridentate (1, 2, 3-triazol-4-yl)-picolinamide (tzpa) ligand

IN Hegarty, DE Barry, JP Byrne, O Kotova… - Chemical …, 2023 - pubs.rsc.org
The chiral bis-tridentate (1, 2, 3-triazol-4-yl)-picolinamide (tzpa) ligand 1 was used in the
formation of lanthanide di-and triple stranded di-metallic helicates in acetonitrile solution …

Lanthanide luminescent di-metallic triple-stranded helicates formed from bis-tridentate (1, 2, 3-triazol-4-yl)-picolinamide (tzpa) ligands and their higher order self …

DE Barry, O Kotova, NA O'Shea… - Materials Chemistry …, 2025 - pubs.rsc.org
The bis-tridentate (1, 2, 3-triazol-4-yl)-picolinamide (tzpa) ligands 1 and 2 were used in the
formation of the luminescent di-metallic Tb (III) triple stranded helicates 3 and 4 (L3Tb2; L= 1 …

Tuning and reviving the luminescence of a new class of pyridyl β-diketonate Eu (III) metallomesogens: From molecules to entrapment in polymer particles

B González-Tobío, F Duarte, A Arribas-Delgado… - Dyes and …, 2022 - Elsevier
A new class of polynuclear Eu (III) compounds bearing pyridyl β-diketonate ligands have
been synthesised, and their thermal and photophysical behaviour studied. Since they …

Subtle adjustments for constructing multi-nuclear luminescent lanthanide organic polyhedra with triazole-based chelates

XQ Guo, LP Zhou, SJ Hu, QF Sun - Dalton Transactions, 2024 - pubs.rsc.org
Controlled self-assembly of predetermined multi-nuclear lanthanide organic polyhedra
(LOPs) still presents a challenge, primarily due to the unpredictable coordination numbers …

Unravelling the formation pathway and energetic landscape of lanthanide cages based on bis-β-diketonato ligands

M Rando, A Carlotto, S Carlotto, R Seraglia… - Inorganic Chemistry …, 2025 - pubs.rsc.org
This study focuses on the self-assembly mechanisms of triple-and quadruple-stranded
lanthanide cages and their solution behaviour, particularly concerning equilibrium and cage …

Differentiable Formation of Chiroptical Lanthanide Heterometallic LnnLn'4‐n(L6) (n=0–4) Tetrahedra with C2‐Symmetrical Bis(tridentate) Ligands

KH Yim, CT Yeung, MYM Wong… - … A European Journal, 2022 - Wiley Online Library
Construction of lanthanide heterometallic complex is important for engineering multifunction
molecular containers. However, it remains a challenge because of the similar ionic radii of …