The chemistry of metal organic framework materials

SE Skrabalak, R Vaidhyanathan - Chemistry of Materials, 2023 - ACS Publications
The journal started its 35th year by celebrating 35 recent manuscripts in a virtual issue that
highlighted diverse materialsbased research: battery materials, MXenes and layered …

One atom can make all the difference: gas-induced phase transformations in bisimidazole-linked diamondoid coordination networks

K Koupepidou, VI Nikolayenko… - Journal of the …, 2023 - ACS Publications
Coordination networks (CNs) that undergo gas-induced transformation from closed
(nonporous) to open (porous) structures are of potential utility in gas storage applications …

Control over phase transformations in a family of flexible double diamondoid coordination networks through linker ligand substitution

K Koupepidou, VI Nikolayenko, D Sensharma… - Chemistry of …, 2023 - ACS Publications
In this work, we present the first metal–organic framework (MOF) platform with a self-
penetrated double diamondoid (ddi) topology that exhibits switching between closed …

Multivariate Flexible Metal–Organic Frameworks and Covalent Organic Frameworks

SK Sobczak, J Drwęska, W Gromelska, K Roztocki… - Small, 2024 - Wiley Online Library
Precise control of the void environment, achieved through multiple functional groups and
enhanced by structural adaptations to guest molecules, stands at the forefront of scientific …

Theoretical and Experimental Insights into the Spatial Distribution of Functional Groups in a Multivariate Flexible Metal–Organic Framework

K Roztocki, MK Dudek, M Szufla, F Formalik… - Chemistry of …, 2024 - ACS Publications
Dynamic multicomponent metal–organic frameworks, comprising numerous functional
groups attached to a flexible backbone, expedite the complexity of coordination chemistry …

Exploring the Influence of Linker Substitution and Ratios on Cooperative Framework Flexibility through the Mixed-Linker Approach

A Halder, CM McGuirk - Crystal Growth & Design, 2024 - ACS Publications
Cooperatively flexible metal–organic frameworks that exhibit step-shaped, or Type V-like,
adsorption–desorption profiles can lower requisite pressure–temperature swings and thus …

Effect of polymorphism on the sorption properties of a flexible square-lattice topology coordination network

A Subanbekova, AA Bezrukov, V Bon… - … Applied Materials & …, 2024 - ACS Publications
The stimulus-responsive behavior of coordination networks (CNs), which switch between
closed (nonporous) and open (porous) phases, is of interest because of its potential utility in …

Reticular Synthesis of Flexible Rare‐Earth Metal‐Organic Frameworks: Control of Structural Dynamics and Sorption Properties Through Ligand Functionalization

E Loukopoulos, GK Angeli… - … A European Journal, 2024 - Wiley Online Library
An exciting direction in metal‐organic frameworks involves the design and synthesis of
flexible structures which can reversibly adapt their structure when triggered by external …

Modulation of the Dynamics of a Two-Dimensional Interweaving Metal–Organic Framework through Induced Hydrogen Bonding

P Fernández-Seriñán, K Roztocki, V Safarifard… - Inorganic …, 2024 - ACS Publications
Inducing, understanding, and controlling the flexibility in metal–organic frameworks (MOFs)
are of utmost interest due to the potential applications of dynamic materials in gas-related …

Exploring porosity in a flexible 3D organic–inorganic {Zn II3 (4DPNDI)[WV (CN) 8] 2} coordination network

K Jędrzejowska, J Kobylarczyk, TM Muzioł… - Chemical …, 2024 - pubs.rsc.org
A 2D cyanido-bridged architecture ZnII-[WV (CN) 8] 3− is smoothly pillared by N, N′-di-(4-
pyridyl)-1, 4, 5, 8-naphthalenetetracarboxydiimide (4DPNDI) into 3D hybrid porous …