Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

The incorporation of heteroatom-containing weak bonds along polymer backbones has
become a popular tool to accelerate degradation. Many methods have already been …

Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction
conditions. Reactive acyl radicals, generated from various acyl precursors such as …

Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal
complexes via singlet‐metal‐carbene intermediates. However, previous transition‐metal …

Although the synthesis of common cyclopropenes has been well studied, the access to
cyclopropenols is rather limited. Herein, we report the first synthesis of α‐trifluoromethylated …

The transition metal‐catalyzed cross‐coupling reaction with Fischer metal carbene
intermediates bearing an electron‐rich alkoxyl or siloxyl group remains a big challenge due …

A cobalt-catalyzed highly Markovnikov-type and enantioselective hydrosilylation of alkenes
is developed for the efficient synthesis of valuable chiral dihydrosilanes. This protocol is …

Materials capable of degradation upon exposure to light hold promise in a diverse range of
applications including biomedical devices and smart coatings. Despite the rapid access to …

Photopolymerization and its application in the dental, three‐dimensional (3D) printing,
coating and electronic industry has become increasingly popular over the last decades. A …

Herein, we report the synthesis of protected 1, 2-amino alcohols starting from carbonyl
compounds and α-silyl amines. The reaction is enabled by a Cr/photoredox dual catalytic …