The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

This work introduces the use of 8-aminoquinoline subcomponents to generate complex
three-dimensional structures. Together with a tris (formylpyridine), 8-aminoquinoline …

This review offers a broad overview of the advancements in anion receptor chemistry in
2021 and 2022. Detailed examples of acclaimed work in fundamental recognition, sensing …

Here we report the formation of an unexpected and unique family of chiral helicates. Crystal
structures show that these triple‐stranded ZnII2L3 complexes are held together by …

Metal–organic self-assembly with flexible moieties is a budding field of research due to the
possibility of the formation of unique architectures. Tetrazole, characterised by four nitrogen …

Recently developed self-assembly strategies allow to rationally reduce the symmetry of
metallosupramolecular architectures. In addition, the combination of multiple ligand types …

Anions have been used to regulate the structures and luminescence of heterometallic
clusters. Introducing ClO4− into orange‐emissive, butterfly‐like [(C)(Au‐PPhpy2) 6Ag4](BF4) …

A double‐walled tetrahedral metal‐organic cage assembled in solution from silver (I), 2‐
formyl‐1, 8‐naphthyridine, halide, and a threefold‐symmetric triamine. The AgI4X clusters at …

A penta-stranded helicate was obtained by combining [Pd (CH3CN) 4](BF4) 2 with La (NO3)
3 and a polydentate ligand. The helicate displays low symmetry, both in solution and in the …

Subcomponent self-assembly relies on cation coordination whereas the roles of anions
often only emerge during the assembly process. When sites for anions are instead pre …