Electrochemical and Non-Electrochemical Pathways in the Electrocatalytic Oxidation of Monosaccharides and Related Sugar Alcohols into Valuable Products

MPJM van der Ham, J Creus, JH Bitter… - Chemical …, 2024 - ACS Publications
In this contribution, we review the electrochemical upgrading of saccharides (eg, glucose)
and sugar alcohols (eg, glycerol) on metal and metal-oxide electrodes by drawing …

Molecular Electro (Photo) Catalysis: Triarylamine and Triarylimidazole Derivatives Mediated Oxidation Systems in Organic Electrosynthesis

S Liu, L Ma, F Hao, W Gao, B Li, S Liu… - Advanced Synthesis …, 2024 - Wiley Online Library
Organic electrosynthesis has become a green, efficient and sustainable alternative to
traditional organic transformation for the redox reactions. In this connection, indirect …

Photoelectrochemical nickel-catalyzed carboacylation/silanoylation of alkenes with unactivated C/Si–H bonds

L Wang, X Huo, X He, L Ackermann, D Wang - Green Chemistry, 2024 - pubs.rsc.org
Direct and selective installation of two different functional groups into the unsaturated bonds
of alkenes constitutes a long-standing goal in organic synthesis. Herein, we first report a …

A Voltage-Controlled Strategy for Modular Shono-Type Amination

S Su, Y Guo, B Parnitzke, T Poerio… - Journal of the American …, 2024 - ACS Publications
Shono-type oxidation to generate functionalized heterocycles is a powerful method for late-
stage diversification of relevant pharmacophores; however, development beyond oxygen …

Enhanced electrochromic properties and amphoteric coloration of V-doped WO 3 supported by electronic structure optimization and oxygen vacancy-mediated Li+ …

S Nie, M Ruan, Y Lian, L Zhao, J Shi… - Journal of Materials …, 2024 - pubs.rsc.org
As one of the most valuable electrochromic materials with in-depth multi-disciplinary
applications, tungsten oxide (WO3) has the advantages of strong energy-saving ability and …

Alkene Cyclopropanation with gem-Dichloroalkanes Catalyzed by (PNN)Co Complexes: Scope and Mechanism

B Cao, G Liu, Z Huang - ACS Catalysis, 2024 - ACS Publications
Highly regioselective and diastereoselective cis-arylcyclopropanation (ACP) and trans-
vinylcyclopropanation (VCP) of 1-alkenes with gem-dichloroalkanes are described. By …

Scaling-Free Cathodes: Enabling Electrochemical Extraction of High-Purity Nano-CaCO3 and -Mg(OH)2 in Seawater

W Kang, S Meng, Y Zhao, J Xu, S Wu… - Environmental …, 2024 - ACS Publications
For electrochemical application in seawater or brine, continuous scaling on cathodes will
form insulation layers, making it nearly impossible to run an electrochemical reaction …

Electrochemical Nickel‐Catalyzed Hydrogenation

L Li, X Wang, N Fu - Angewandte Chemie, 2024 - Wiley Online Library
Olefin hydrogenation is one of the most important transformations in organic synthesis.
Electrochemical transition metal‐catalyzed hydrogenation is an attractive approach to …

An Electrochemical Pipette for the Study of Drug Metabolite

N Nikzad, BT Punchihewa, V Minda… - Analytical …, 2024 - ACS Publications
Electrochemistry offers an effective means of mimicking enzymatic metabolic pathways,
particularly the oxidative pathways catalyzed by the cytochrome P450 superfamily. The …

Electrosynthesis of Verdoheme and Biliverdin Derivatives Following Enzymatic Pathways

A Lashgari, X Wang, JA Krause, S Sinha… - Journal of the …, 2024 - ACS Publications
Artificial syntheses of biologically active molecules have been fruitful in many bioinspired
catalysis applications. Specifically, verdoheme and biliverdin, bearing polypyrrole …