Conspectus In organic synthesis, ligand-modified copper (I) hydride (CuH) complexes have
become well-known reagents and catalysts for selective reduction, particularly toward …

The asymmetric catalytic synthesis of 1, 2-diamines has received considerable interest,
especially in the last ten years, due to their presence in biologically active compounds and …

Nitrogen (N) is ubiquitously found in bioactive molecules, pharmaceutical agents, and
organic functional materials. Accordingly, development of new C–N bond-forming catalysis …

Regiodivergent alkene functionalization that produces either regioisomer starting from the
same raw materials is desirable. Herein, we report a nickel‐catalyzed switchable site …

Reported herein is a modular, NiH-catalyzed system capable of proximal-selective
hydroamination of unactivated alkenes with diverse amine sources. The key to the …

Despite the frequent occurrence of γ-branched amines in bioactive molecules, the direct
catalytic asymmetric synthesis of this structural motif containing a remote stereocenter …

Enantioenriched 1, 2-and 1, 3-diamines with chiral α-branched aliphatic amine motifs are
important substructures in bioactive compounds and related molecules and serve as …

Classical amination methods involve the reaction of a nitrogen nucleophile with an
electrophilic carbon center; however, in recent years, umpoled strategies have gained …

Diamination of alkenes represents an attractive way to generate differentiated vicinal
diamines, which are prevalent motifs in biologically active compounds and catalysts …

We present herein an unprecedented diastereoconvergent synthesis of vicinal diamines
from diols through an economical, redox‐neutral process. Under cooperative ruthenium and …