Light-induced spin crossover in Fe (II)-based complexes: The full photocycle unraveled by ultrafast optical and X-ray spectroscopies

A Cannizzo, CJ Milne, C Consani, W Gawelda… - Coordination Chemistry …, 2010 - Elsevier
The light-induced spin and structure changes upon excitation of the singlet metal-to-ligand
charge transfer (1MLCT) state of Fe (II)-polypyridine complexes are investigated in detail in …

Femtosecond structural dynamics drives the trans/cis isomerization in photoactive yellow protein

K Pande, CDM Hutchison, G Groenhof, A Aquila… - Science, 2016 - science.org
A variety of organisms have evolved mechanisms to detect and respond to light, in which the
response is mediated by protein structural changes after photon absorption. The initial step …

Photochemical reactions in biological systems: probing the effect of the environment by means of hybrid quantum chemistry/molecular mechanics simulations

M Boggio-Pasqua, CF Burmeister, MA Robb… - Physical Chemistry …, 2012 - pubs.rsc.org
Organisms have evolved a wide variety of mechanisms to utilize and respond to light. In
many cases, the biological response is mediated by structural changes that follow photon …

Surface states mediate triplet energy transfer in nanocrystal–acene composite systems

JA Bender, EK Raulerson, X Li, T Goldzak… - Journal of the …, 2018 - ACS Publications
Hybrid organic: inorganic materials composed of semiconductor nanocrystals functionalized
with acene ligands have recently emerged as a promising platform for photon upconversion …

Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads

MT Whited, NM Patel, ST Roberts, K Allen… - Chemical …, 2012 - pubs.rsc.org
We report the synthesis and characterization of symmetric BODIPY dyads where the
chromophores are attached at the meso position, using either a phenylene bridge or direct …

On the interplay between charge, spin and structural dynamics in transition metal complexes

M Chergui - Dalton Transactions, 2012 - pubs.rsc.org
This perspective presents some recent results concerning ultrafast intramolecular relaxation
processes in metal-based molecular complexes. Ultrafast electronic/vibrational relaxation at …

Incoherent manipulation of the photoactive yellow protein photocycle with dispersed pump-dump-probe spectroscopy

DS Larsen, IHM van Stokkum, M Vengris… - Biophysical journal, 2004 - cell.com
Photoactive yellow protein is the protein responsible for initiating the" blue-light vision" of
Halorhodospira halophila. The dynamical processes responsible for triggering the …

Coherent ultrafast torsional motion and isomerization of a biomimetic dipolar photoswitch

J Briand, O Bräm, J Réhault, J Léonard… - Physical Chemistry …, 2010 - pubs.rsc.org
Femtosecond fluorescence up-conversion, UV-Vis and IR transient absorption spectroscopy
are used to study the photo-isomerization dynamics of a new type of zwitterionic photoswitch …

Confinement in crystal lattice alters entire photocycle pathway of the Photoactive Yellow Protein

PE Konold, E Arik, J Weißenborn, JC Arents… - Nature …, 2020 - nature.com
Femtosecond time-resolved crystallography (TRC) on proteins enables resolving the spatial
structure of short-lived photocycle intermediates. An open question is whether confinement …

Excited-state self-trapping and ground-state relaxation dynamics in poly (3-hexylthiophene) resolved with broadband pump–dump–probe spectroscopy

E Busby, EC Carroll, EM Chinn, L Chang… - The Journal of …, 2011 - ACS Publications
Broadband femtosecond transient absorption spectroscopy is used to explore the
mechanisms underlying excited-state and ground-state exciton relaxation in poly (3 …