[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
Mussel-inspired fabrication of functional materials and their environmental applications: progress and prospects
Mussel-inspired chemistry has recently emerged as one of the most important and interest
surface modification method owing to its gentle experiment conditions, high modification …
surface modification method owing to its gentle experiment conditions, high modification …
Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …
Kinetics of atom transfer radical polymerization
P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …
Copper (II)/tertiary amine synergy in photoinduced living radical polymerization: Accelerated synthesis of ω-functional and α, ω-heterofunctional poly (acrylates)
Photoinduced living radical polymerization of acrylates, in the absence of conventional
photoinitiators or dye sensitizers, has been realized in “daylight'” and is enhanced upon …
photoinitiators or dye sensitizers, has been realized in “daylight'” and is enhanced upon …
Precise polymer synthesis by autonomous self‐optimizing flow reactors
M Rubens, JH Vrijsen, J Laun… - Angewandte Chemie …, 2019 - Wiley Online Library
A novel continuous flow system for automated high‐throughput screening, autonomous
optimization, and enhanced process control of polymerizations was developed. The …
optimization, and enhanced process control of polymerizations was developed. The …
Polymer synthesis in continuous flow reactors
A variety of polymerizations has long been performed in continuous flow reactors on an
industrial scale; comparatively, on smaller scales, continuous polymerization methods have …
industrial scale; comparatively, on smaller scales, continuous polymerization methods have …
Copolymers with controlled molecular weight distributions and compositional gradients through flow polymerization
We report a novel semicontinuous method for producing polymer mixtures with tailored
molecular weight distributions (MWDs) and chemical compositions. In contrast to recent …
molecular weight distributions (MWDs) and chemical compositions. In contrast to recent …
Photoinduced sequence-control via one pot living radical polymerization of acrylates
The ability to regulate the activation and deactivation steps via an external stimulus has
always been a challenge in polymer chemistry. In an ideal photo-mediated system, whereby …
always been a challenge in polymer chemistry. In an ideal photo-mediated system, whereby …
Single-electron transfer living radical polymerization platform to practice, develop, and invent
The most fundamental aspects of single-electron transfer (SET) principles are presented.
They are discussed according to different definitions used by expert practitioners and are …
They are discussed according to different definitions used by expert practitioners and are …