There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

Rare-earth ions are characterized by large unquenched orbital angular momentum
associated with the internal nature of the valence f orbitals. In fact, with the exception of …

Due to their usual large magnetic moments and large magnetic anisotropy lanthanide ions
are investigated for the search of Single Molecule Magnets with high blocking temperature …

Heterometallic 3d− 4f complexes are of high interest in molecular magnetism: the lanthanide
ions bring large and, in most cases, anisotropic magnetic moments. The combination of 3d …

Heterometallic complexes containing 3d-/4f-metals have been made with a variety of ligands
including Schiff-bases, pyridonates and amino-alcohols. The majority of species with Schiff …

Six tetranuclear complexes [Fe (III) 3 Ln (μ 3-O) 2 (CCl 3 COO) 8 (H 2 O)(THF) 3]⋅ THF⋅ C 7
H 16 [Ln= Gd (III)(1), Tb (III)(2), Dy (III)(3), Ho (III)(4), Y (III)(5), and Lu (III)(6)] have been …

d–f Heteronuclear complexes: synthesis, structures and physicochemical aspects -
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Interest in porous metal-coordination polymers that are constructed by self-assembly
processes has mushroomed recently,[1] because of their use in, for example, redox …

Magnetic lanthanide–transition-metal hybrid materials have enjoyed increasing attraction
because they not only provide examples for studying magnetic coupling involving …

Heterometallic 3d‐4f complexes are being investigated, for some time, as being useful in
molecular magnetism, particularly as single‐molecule magnets (SMMs). This interest is …