Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Multicomponent reactions and photo/electrochemistry join forces: atom economy meets energy efficiency

GA Coppola, S Pillitteri, EV Van der Eycken… - Chemical Society …, 2022 - pubs.rsc.org
Visible-light photoredox catalysis has been regarded as an extremely powerful tool in
organic chemistry, bringing the spotlight back to radical processes. The versatility of …

Direct Synthesis of Sulfonamides via Synergetic Photoredox and Copper Catalysis

M Zhang, L Liu, B Wang, Y Yang, Y Liu, Z Wang… - ACS …, 2023 - ACS Publications
Despite the frequent occurrence of sulfonamides in contemporary pharmaceuticals and
agrochemicals, the synthesis of these compounds is limited by the availability of preexisting …

Photocatalytic direct decarboxylation of carboxylic acids to derivatize or degrade polymers

A Adili, AB Korpusik, D Seidel… - Angewandte Chemie …, 2022 - Wiley Online Library
Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

Photocatalytic Carboxylate to Sulfinamide Switching Delivers a Divergent Synthesis of Sulfonamides and Sulfonimidamides

JA Andrews, J Kalepu, CF Palmer… - Journal of the …, 2023 - ACS Publications
sulfinamides, sulfonamides, and sulfonimidamides are in-demand motifs in medicinal
chemistry, yet methods for the synthesis of alkyl variants that start from simple, readily …

Radical approaches to C–S bonds

Z Wu, DA Pratt - Nature Reviews Chemistry, 2023 - nature.com
Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals,
materials and flavourants. Historically, these moieties were introduced almost exclusively …

[HTML][HTML] Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation

VT Nguyen, GC Haug, VD Nguyen, NTH Vuong… - Chemical …, 2022 - pubs.rsc.org
The reactivity of the sulfonyl group varies dramatically from nucleophilic sulfinates through
chemically robust sulfones to electrophilic sulfonyl halides—a feature that has been used …

[HTML][HTML] Advances in photochemical and electrochemical incorporation of sulfur dioxide for the synthesis of value-added compounds

SP Blum, K Hofman, G Manolikakes… - Chemical …, 2021 - pubs.rsc.org
Organic photochemistry and electrochemistry currently receive tremendous attention in
organic synthesis as both techniques enable the reagent-less activation of organic …

[HTML][HTML] Kinetically-driven reactivity of sulfinylamines enables direct conversion of carboxylic acids to sulfinamides

HT Dang, A Porey, S Nand, R Trevino… - Chemical …, 2023 - pubs.rsc.org
Sulfinamides are some of the most centrally important four-valent sulfur compounds that
serve as critical entry points to an array of emergent medicinal functional groups, molecular …

Free carboxylic acids: the trend of radical decarboxylative functionalization

L Li, Y Yao, N Fu - European Journal of Organic Chemistry, 2023 - Wiley Online Library
The exceptional versatility of carboxylic acids has been extensively exploited in organic
synthesis across several decades. There has been a recent upsurge of radical …