N–N bond cleavage of hydrazines on transition metals is of considerable importance in
understanding the mechanism of biological nitrogen fixation under ambient conditions. We …

Two-electron reactivity of [N2O2red] ZrL3 (1a, N2O2red= N, N '-bis (3, 5-di-tert-butyl-2-
phenoxy)-1, 2-phenylenediamide, L= THF) was explored with halogens and 1, 2 …

Various dienes and a triene can be regioselectively diaminated at the internal double bond
with good yields and high diastereoselectivity using di-tert-butyldiaziridinone (5) as the …

Recent developments in the chemistry of homo-and heterometallic clusters of Iron, Cobalt
and Nickel triads substituted with alkynes and related ligands are examined. New synthetic …

Addition of stoichiometric quantites of 1, 2-diarylhydrazines to the bis (imino) pyridine
vanadium dinitrogen complex,[{(i PrBPDI) V (THF)} 2 (μ2-N2)](i PrBPDI= 2, 6-(2, 6-i Pr2 …

Coordinatively unsaturated transition-metal compounds stabilized by supplemental electron
donation from π-basic ligands are described as “operationally unsaturated”. Such …

A series of alkali metal cerium diphenylhydrazido complexes, Mx (py) y [Ce (PhNNPh) 4], M=
Li, Na, and K, x= 4 (Li and Na) or 5 (K), and y= 4 (Li), 8 (Na), or 7 (K), were synthesized to …

Bifunctional catalysts, in which two functionalities cooperate in substrate activation and
transformation, promote a number of chemical and biological reactions quite efficiently. This …

The methoxy-bridged RuII complex [Cp∧ Ru (μ-OMe)] 2 (Cp∧= η5-1-methoxy-2, 4-di-tert-
butyl-3-neopentylcyclopentadienyl) was obtained from the RuIII complex [Cp∧ RuCl (μ-Cl)] …

The sterically hindered Fe (II) thiolate dimer Fe2 (μ-STriph) 2 (STriph) 2 (1;[STriph]−= 2, 4, 6-
triphenylbenzenethiolate) reacts with primary amines (t BuNH2, aniline) and N2H4 to form …