Why is ferrocene so exceptional?

D Astruc - European Journal of Inorganic Chemistry, 2017 - Wiley Online Library
The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …

[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

(Multi) ferrocenyl five-membered heterocycles: excellent connecting units for electron transfer studies

A Hildebrandt, H Lang - Organometallics, 2013 - ACS Publications
The electro-and spectroelectrochemical behavior of diverse (multi) ferrocenyl five-
membered heterocyclic compounds, including furan, thiophene, pyrroles, phospholes, etc. is …

Charge delocalization in a cyclometalated bisruthenium complex bridged by a noninnocent 1, 2, 4, 5-tetra (2-pyridyl) benzene ligand

CJ Yao, YW Zhong, J Yao - Journal of the American Chemical …, 2011 - ACS Publications
Two ruthenium atoms are covalently connected to the para positions of a phenyl ring in 1, 2,
4, 5-tetra (2-pyridyl) benzene (tpb) to form a linear Ru–tpb–Ru arrangement. This unique …

Electronic coupling in 1, 2, 3-triazole bridged ferrocenes and its impact on reactive oxygen species generation and deleterious activity in cancer cells

P Biegański, E Kovalski, N Israel, E Dmitrieva… - Inorganic …, 2022 - ACS Publications
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for
testing theories of electron transfer and in attempts to design molecular-scale electronic …

Influence of electron delocalization in heterocyclic core systems on the electrochemical communication in 2, 5-Di-and 2, 3, 4, 5-Tetraferrocenyl thiophenes, furans, and …

A Hildebrandt, D Schaarschmidt, R Claus… - Inorganic …, 2011 - ACS Publications
A series of 2, 5-di-and 2, 3, 4, 5-tetraferrocenyl-substituted thiophenes, furans, and pyrroles
were synthesized using the Negishi C, C cross-coupling protocol. The electronic and …

Di-and triferrocenyl (hetero) aromatics: Synthesis, characterization,(spectro-) electrochemistry, and calculations

U Pfaff, A Hildebrandt, D Schaarschmidt, T Hahn… - …, 2012 - ACS Publications
A series of di-and triferrocenyl (hetero) aromatics including 2, 5-diferrocenylpyridine (4), 2, 6-
diferrocenylpyridine (5), 1, 3, 5-triferrocenylbenzene (9), 2, 4, 6-triferrocenylpyridine (10) …

Synthesis and charge-transfer dynamics in a ferrocene-containing organoboryl aza-BODIPY donor–acceptor triad with boron as the hub

E Maligaspe, TJ Pundsack, LM Albert… - Inorganic …, 2015 - ACS Publications
AN, N′-bis (ferroceneacetylene) boryl complex of 3, 3′-diphenylazadiisoindolylmethene
was synthesized by the reaction of an N, N′-difluoroboryl complex of 3, 3 …

Electron transfer studies on ferrocenylthiophenes: synthesis, properties, and electrochemistry

JM Speck, R Claus, A Hildebrandt, T Rüffer… - …, 2012 - ACS Publications
The ferrocenylthiophenes 2, 3-Fc2-c C4H2S (9), 2, 4-Fc2-c C4H2S (10), and 2, 3, 4-Fc3-c
C4HS (11) have been prepared by a 2-or 3-fold Negishi cross-coupling reaction of the …

Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …