Using physical organic chemistry to shape the course of electrochemical reactions

KD Moeller - Chemical reviews, 2018 - ACS Publications
While organic electrochemistry can look quite different to a chemist not familiar with the
technique, the reactions are at their core organic reactions. As such, they are developed and …

Quinone‐catalyzed selective oxidation of organic molecules

AE Wendlandt, SS Stahl - Angewandte Chemie International …, 2015 - Wiley Online Library
Quinones are common stoichiometric reagents in organic chemistry. Para‐quinones with
high reduction potentials, such as DDQ and chloranil, are widely used and typically promote …

Thermodynamic and kinetic considerations for the reaction of semiquinone radicals to form superoxide and hydrogen peroxide

Y Song, GR Buettner - Free Radical Biology and Medicine, 2010 - Elsevier
The quinone/semiquinone/hydroquinone triad (Q/SQ•−/H2Q) represents a class of
compounds that has great importance in a wide range of biological processes. The half-cell …

Synthetic applications of hydride abstraction reactions by organic oxidants

JL Miller, JMIA Lawrence, FOR Del Rey… - Chemical Society …, 2022 - pubs.rsc.org
Carbon–hydrogen bond functionalizations provide an attractive method for streamlining
organic synthesis, and many strategies have been developed for conducting these …

Enantioselective Aerobic Oxidative C(sp3)–H Olefination of Amines via Cooperative Photoredox and Asymmetric Catalysis

G Wei, C Zhang, F Bureš, X Ye, CH Tan, Z Jiang - ACS Catalysis, 2016 - ACS Publications
A cooperative photoredox and asymmetric catalysis for the enantioselective aerobic
oxidative C (sp3)–H olefination of tetrahydro-β-carbolines (THCs) is reported. This method …

Oxidative and Enantioselective Cross‐Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether

Y Hayashi, T Itoh, H Ishikawa - Angewandte Chemie International Edition, 2011 - infona.pl
Synthetically important β‐substituted γ‐nitro aldehydes have been synthesized with
excellent enantioselectivity by the cross‐coupling reaction of β‐aryl substituted aldehydes or …

Palladium-catalyzed dehydrogenative β′-functionalization of β-keto esters with indoles at room temperature

MV Leskinen, KT Yip, A Valkonen… - Journal of the American …, 2012 - ACS Publications
The dehydrogenative β′-functionalization of α-substituted β-keto esters with indoles
proceeds with high regioselectivities (C3-selective for the indole partner and β′-selective …

Total Synthesis of Hapalindole‐Type Natural Products

Z Lu, M Yang, P Chen, X Xiong, A Li - Angewandte Chemie, 2014 - Wiley Online Library
A unified and bioinspired oxidative cyclization strategy was used in the first total syntheses
of naturally occurring 12‐epi‐hapalindole Q isonitrile, hapalonamide H, deschloro 12‐epi …

Predictive model for oxidative C–H bond functionalization reactivity with 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone

CA Morales-Rivera, PE Floreancig… - Journal of the American …, 2017 - ACS Publications
2, 3-Dichloro-5, 6-dicyano-1, 4-benzoquinone (DDQ) is a highly effective reagent for
promoting C–H bond functionalization. The oxidative cleavage of benzylic and allylic C–H …

2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ)/tert‐Butyl Nitrite/Oxygen: A Versatile Catalytic Oxidation System

Z Shen, J Dai, J Xiong, X He, W Mo… - Advanced Synthesis …, 2011 - Wiley Online Library
A new catalytic oxidation system using catalytic amounts of 2, 3‐dichloro‐5, 6‐dicyano‐1, 4‐
benzoquinone (DDQ) and tert‐butyl nitrite with molecular oxygen serving as the …