An Update on General Chemiexcitation Mechanisms in Cyclic Organic Peroxide Decomposition and the Chemiluminescent Peroxyoxalate Reaction in Aqueous …

MC Cabello, FH Bartoloni… - Photochemistry and …, 2023 - Wiley Online Library
Four‐membered ring peroxides are intimately linked to chemiluminescence and
bioluminescence transformations, as high‐energy intermediates responsible for …

Chemiluminescent peroxyoxalate cellulose microspheres

MC Cabello, OA El Seoud, EL Bastos… - Journal of Photochemistry …, 2024 - Elsevier
The sustainable application of chemiluminescence technology benefits from the
development of efficient chemiluminescent reactions in water. The peroxyoxalate reaction is …

Bright and long‐lasting aqueous peroxyoxalate chemiluminescence in cellulose microspheres

MC Cabello, EL Bastos, OAA El Seoud… - Photochemistry and …, 2024 - Wiley Online Library
Water decreases the brightness of the peroxyoxalate chemiluminescence partially due to the
hydrolysis of the oxalate reagent. Here, we show that encapsulation of an oxalate ester and …

Water modulates the chemiexcitation efficiency of the peroxyoxalate reaction: Enhancement at low and decrease at higher concentrations

MC Cabello, MPO Lemos, WJ Baader - Journal of Photochemistry and …, 2024 - Elsevier
Chemiluminescence transformations are widely utilized in analytical and bioanalytical
applications. Specifically, the peroxyoxalate system can be employed for sensitive …

Estudos cinéticos e mecanísticos da reação peroxioxalato em meio aquoso contendo surfactante

MPO Lemos - 2022 - teses.usp.br
A reação peroxioxalato, desde a sua descoberta, tem sido bastante estudada com
abordagens cinéticas e mecanísticas e amplamente utilizada para fins analíticos. A maioria …