Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

A single-crystal X-ray diffraction (XRD) study of diaryliodonium tetrachloroaurates (or, in the
recent terminology, tetrachloridoaurates),[(p-XC6H4) 2I][AuCl4](X= Cl, 1; Br, 2), was …

Five new copper (I) complexes─ composed of the paired dibenzohalolium and [CuL2]−(L=
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …

Synthesis and X-ray characterization of the four diaryliodonium tetrachloroplatinates
(II)[Ar1Ar2I] 2 [PtCl4](Ar1/Ar2= Ph/Ph (1), 4-Cl-C6H4/2, 4, 6-(MeO) 3C6H2 (2), 4-Me-C6H4/2 …

Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field
of organic synthesis. The three center, four electron (3c–4e) bond is a center piece of their …

Co-crystallization of dithiocarbamate complexes [MII (S2CNEt2) 2](M= Cu 1, Ni 2, Pd 3, Pt 4)
and 1, 3, 5-triiodotrifluorobenzene (FIB) gives an isomorphic series of (1–4)· 2FIB co-crystals …

Methanol reforming has been a popular pathway to produce hydrogen due to the high
hydrogen storage density of methanol. CeO 2 as the support is widely used for catalytic …

The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …

In the context of the ever-growing interest in the cyclic diaryliodonium salts, this work
presents synthetic design principles for a new family of structures with two hypervalent …

The supramolecular dimensionality of halogen bonded architectures formed in the solid
state by diaryliodonium salts is greater when the anion is a disulfonate rather than a …