Pure shift edited NMR methodologies for the extraction of Homo-and heteronuclear couplings with ultra-high resolution

SK Mishra, N Suryaprakash - Progress in Nuclear Magnetic Resonance …, 2023 - Elsevier
The scalar couplings that result in the splitting of the signals in the NMR spectrum arise due
to the interaction of the nuclear spins, whereby the spin polarization is transmitted through …

Efficient determination of scalar coupling networks by band selective decoupled 2D NMR spectroscopy

H Zhan, C Gao, C Huang, X Lin, Y Huang, Z Chen - Analytica Chimica Acta, 2023 - Elsevier
Scalar (J) couplings constitute one of vital features observed in NMR spectroscopy and
show valuable information for molecular structure elucidation and conformation analysis …

Computer‐Assisted 3D Structure Elucidation (CASE‐3D): The Structural Value of 2JCH in Addition to 3JCH Coupling Constants

MRM Koos, A Navarro‐Vázquez… - Angewandte Chemie …, 2020 - Wiley Online Library
We present a method to use long‐range CH coupling constants to derive the correct
diastereoisomer from the molecular constitution of small molecules. A set of 79 2JCH and …

Improved detection limits of J‐coupled neurometabolites in the human brain at 7 T with a J‐refocused sLASER sequence

C Najac, VO Boer, HE Kan, AG Webb… - NMR in …, 2022 - Wiley Online Library
In a standard spin echo, the time evolution due to homonuclear couplings is not reversed,
leading to echo time (TE)‐dependent modulation of the signal amplitude and signal loss in …

New Discorhabdin D Analogues from Latrunculia spp. Sponges

M Orfanoudaki, M Dalilian, L Du, CH Chau… - Journal of Natural …, 2024 - ACS Publications
Chemical profiles of Latrunculia kaakaariki and Latrunculia brevis were investigated,
resulting in the isolation of five new discorhabdin D derivatives 1 and 3–6. Their planar …

Simultaneous determination of multiple coupling networks by high-resolution 2D J-edited NMR spectroscopy

H Zhan, C Huang, C Gao, E Lin, Y Huang, Z Chen - Analytica Chimica Acta, 2021 - Elsevier
J coupling constitutes an important NMR parameter for molecular-level composition analysis
and conformation elucidation. Dozens of J-based approaches have been exploited for J …

Fast 2D NMR for Metabolomics

C Praud, MPM Letertre, A Dey, JN Dumez… - 2023 - books.rsc.org
Just like genomics aims to sequence and study the DNA contained in a complex mixture of
organisms at a large scale, as transcriptomics does with RNA and proteomics with proteins …

Simultaneous acquirement of pure shift 2D homonuclear correlation spectra

C Yang, J Chen, Q Zeng, Y Luo, Z Chen… - Journal of Magnetic …, 2022 - Elsevier
Two dimensional homonuclear correlation spectra like COSY, TOCSY and NOESY are
classic two-dimensional spectra for analyzing coupling networks and delivering structural …

Fully Exploiting the Power of 2D NMR J-Resolved Spectroscopy

Q Zeng, J Chen, C Zhan, Y Lin, Z Chen - Analytical Chemistry, 2020 - ACS Publications
Nuclear magnetic resonance (NMR) spectroscopy is a powerful analytical tool that enables
one to study molecular properties and interactions. Homonuclear couplings provide …

Selective homonuclear 2D J-resolved spectroscopy

D Sinnaeve - eMagRes, 2020 - cnrs.hal.science
Selective 2D J-resolved spectroscopy delivers 2D spectra where exclusively homonuclear
couplings to a selected spin feature as doublets along the indirect dimension, facilitating …