In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

We report the development of palladium (0)‐catalyzed syn‐selective 1, 2‐carboboration and‐
silylation reactions of alkenes containing cleavable directing groups. With B2pin2 or …

Direct construction of fully alkyl-substituted tertiary chiral centers remote to activating groups
is highly challenging and desirable. Herein, a Ni-catalyzed enantioselective hydroalkylation …

We have developed a Ni-catalyzed enantioselective hydroarylation of styrenes with
arylboronic acids using MeOH as the hydrogen source, providing an efficient method to …

The precise control of the regioselectivity in the transition metal‐catalyzed migratory
hydrofunctionalization of alkenes remains a big challenge. With a transient ketimine …

We report an enantioselective hydroarylation reaction of styrenes and 1, 3-dienes with
arylboronic acids catalyzed by nickel complexes bearing chiral spiro aminophosphine …

The transition metal-catalyzed hydrofunctionalization of alkenes offers an efficient solution
for the rapid construction of complex functional molecules, and significant progress has …

An enantioselective addition reaction of various alkyl groups to unactivated internal alkenes
under Cu catalysis has been developed. The reaction uses amide-linked aminoquinoline as …

A nickel‐catalyzed regiodivergent hydroarylation and hydroalkenylation of unactivated
alkenyl carboxylic acids is reported, whereby the ligand environment around the metal …

A redox‐relay migratory hydroarylation of isomeric mixtures of olefins with arylboronic acids
catalyzed by nickel complexes bearing diamine ligands is described. A range of structurally …