Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

Hydrogen-atom transfer mediated by earth-abundant transition-metal hydrides (M-Hs) has
emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most …

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

Catalytic hydrogen atom transfer from metal‐hydrides to alkenes allows feedstock olefins to
be used as alkyl radical precursors. The chemoselectivity of this process makes it an …

The current status of homogeneous iron catalysis in organic chemistry is contemplated, as
are the reasons why this particular research area only recently starts challenging the …

The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …

The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …