Ensemble effect for single-atom, small cluster and nanoparticle catalysts

Y Guo, M Wang, Q Zhu, D Xiao, D Ma - Nature Catalysis, 2022 - nature.com
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …

Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2 Reduction

Z Zhang, J Zhu, S Chen, W Sun… - Angewandte Chemie, 2023 - Wiley Online Library
Precise design and tuning of the micro‐atomic structure of single atom catalysts (SACs) can
help efficiently adapt complex catalytic systems. Herein, we inventively found that when the …

Photocatalytic CO2 reduction using La-Ni bimetallic sites within a covalent organic framework

M Zhou, Z Wang, A Mei, Z Yang, W Chen, S Ou… - Nature …, 2023 - nature.com
The precise construction of photocatalysts with diatomic sites that simultaneously foster light
absorption and catalytic activity is a formidable challenge, as both processes follow distinct …

Sulfur vacancy-rich MoS2 as a catalyst for the hydrogenation of CO2 to methanol

J Hu, L Yu, J Deng, Y Wang, K Cheng, C Ma… - Nature Catalysis, 2021 - nature.com
The low-temperature hydrogenation of CO2 to methanol is of great significance for the
recycling of this greenhouse gas to valuable products, however, it remains a great challenge …

Towards the development of the emerging process of CO 2 heterogenous hydrogenation into high-value unsaturated heavy hydrocarbons

J Wei, R Yao, Y Han, Q Ge, J Sun - Chemical Society Reviews, 2021 - pubs.rsc.org
The emerging process of CO2 hydrogenation through heterogenous catalysis into important
bulk chemicals provides an alternative strategy for sustainable and low-cost production of …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis

X Jiang, X Nie, X Guo, C Song, JG Chen - Chemical reviews, 2020 - ACS Publications
The utilization of fossil fuels has enabled an unprecedented era of prosperity and
advancement of well-being for human society. However, the associated increase in …

State of the art and perspectives in heterogeneous catalysis of CO 2 hydrogenation to methanol

J Zhong, X Yang, Z Wu, B Liang, Y Huang… - Chemical Society …, 2020 - pubs.rsc.org
The ever-increasing amount of anthropogenic carbon dioxide (CO2) emissions has resulted
in great environmental impacts. The selective hydrogenation of CO2 to methanol, the first …

CO2 Hydrogenation to Methanol over In2O3-Based Catalysts: From Mechanism to Catalyst Development

J Wang, G Zhang, J Zhu, X Zhang, F Ding… - ACS …, 2021 - ACS Publications
Carbon dioxide (CO2) hydrogenation to methanol with H2 produced with renewable energy
represents a promising path for the effective utilization of a major anthropogenic greenhouse …