Aqueous Li-ion batteries have long been envisioned as safe and green energy storage technology, but have never been commercially realized owing to the limited electrochemical …
The pharmaceutical industry relies extensively on solvents for various purposes, including synthesis, crystallization, purification, solubilization, and developing drug delivery systems …
In highly concentrated salt solutions, the water hydrogen bond (H-bond) network is completely disrupted by the presence of ions. Water is forced to restructure as dictated by …
Aqueous electrolytes are facing substantial barriers for their all-around use in electrochemical energy storage applications due to their limited operating voltage window …
Superconcentrated electrolytes have emerged as a promising class of materials for energy storage devices, with evidence that high voltage performance is possible even with water as …
R Yuan, MD Fayer - The Journal of Physical Chemistry B, 2019 - ACS Publications
Water and ion dynamics in concentrated LiCl solutions were studied using ultrafast 2D IR spectroscopy with the methyl thiocyanate (MeSCN) CN stretch as the vibrational probe. The …
The structural dynamics of highly concentrated LiCl and LiBr aqueous solutions were observed from 1–4 to 1–16 water molecules per ion pair using ultrafast polarization …
J Forero-Saboya, E Hosseini-Bab-Anari… - The journal of …, 2019 - ACS Publications
Water-in-salt and water-in-bisalt electrolytes have recently attracted much attention due to their expanded electrochemical stability windows. The concentration limit of such …
Till now, there has been ambiguity about the structural heterogeneity inside a solute solvation shell and the dynamical response of the surrounding solvent molecules. To …