Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …

The terminal uranium nitride linkage is a fundamental target in the study of f-orbital
participation in metal-ligand multiple bonding but has previously eluded characterization in …

Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

Since uranium has several common paramagnetic oxidation states, ie, 5f 1 U5+, 5f 2 U4+,
and 5f 3 U3+, one of the analytical methods commonly used for characterizing uranium …

The nature and extent of covalency in uranium bonding is still unclear compared with that of
transition metals, and there is great interest in studying uranium–ligand multiple bonds …

The chemistry of f-block metal–carbon multiple bonds is underdeveloped compared to well-
established carbene complexes of the d-block transition metals. Herein, we report two new …

Despite decades of efforts, the actinide–carbon triple bond has remained an elusive target,
defying synthesis in any isolable compound. Herein, we report the successful synthesis of …

We have developed a nickel-catalyzed hydroarylation of alkenes using aryl halides as
coupling partners. Excellent anti-Markovnikov selectivity is achieved with aryl-substituted …

We report attempts to prepare uranyl (VI)-and uranium (VI) carbenes utilizing deprotonation
and oxidation strategies. Treatment of the uranyl (VI)-methanide complex [(BIPMH) UO2Cl …