The most fundamental aspects of single-electron transfer (SET) principles are presented. They are discussed according to different definitions used by expert practitioners and are …
Photoinduced living radical polymerization of acrylates, in the absence of conventional photoinitiators or dye sensitizers, has been realized in “daylight'” and is enhanced upon …
This study reports a highly efficient photoredox catalyst, Ru (bpy) 3Cl2, capable of controlling the polymerization of methacrylates, acrylates, and acrylamides in the presence …
Cu (0)-mediated living radical polymerization or single electron transfer living radical polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …
Atom transfer radical polymerization (ATRP) typically requires various parameters to be optimized in order to achieve a high degree of control over molecular weight and dispersity …
The synthesis of well-defined high molecular weight block copolymers by sequential in situ chain extensions via Cu (0)-mediated living radical polymerization is reported. Optimal …
Single electron transfer–living radical polymerization (SET-LRP) represents a robust and versatile tool for the synthesis of vinyl polymers with well-defined topology and chain end …
The versatile and high yielding functionalization of polymer end groups is a critical tool for controlling material properties and/or for successful post polymerization reactions. In this …
Photoinduced living radical polymerization of acrylates is achieved upon UV irradiation (λmax≈ 360 nm) in the presence of an aliphatic tertiary amine ligand (Me6-Tren) in the …