The stabilization of nitrogen‐rich phases presents a significant chemical challenge due to
the inherent stability of the dinitrogen molecule. This stabilization can be achieved by …

We have synthesized the orthocarbonate Sr3 [CO4] O in a laser-heated diamond anvil cell at
20 and 30 GPa by heating to≈ 3000 (300) K. Afterward, we recovered the orthocarbonate …

We have synthesized Pb [C2O5], an inorganic pyrocarbonate salt, in a laser-heated
diamond anvil cell (LH-DAC) at 30 GPa by heating a Pb [CO3]+ CO2 mixture to≈ 2000 …

CaC2O5-I 4̅2 d was obtained by reacting CO2 and CaCO3 at lower Earth mantle
pressures and temperatures ranging between 34 and 45 GPa and between 2000 and 3000 …

In this study, we present the results of a search for new stable structures of SrC 2 O 5 and
BaC 2 O 5 in the pressure range of 0–100 GPa based on the density functional theory and …

Over the past few years, the concept of carbonates, as the salts of MCO3 or composition with
[CO3] triangles in the crystal structures, was sufficiently extended. In addition to carbonates …

The transition from structures with classical [CO3] triangles to structures with [CO4]
tetrahedra, corresponding to the transition from sp2 to sp3 hybridization of carbon atoms, is …

For the first time, the formation of compound Li 2 C 2 O 5 was demonstrated based on the
first-principles calculations and crystal structure prediction algorithms. This compound is …

The exploration of the physical attributes of the recently discovered orthocarbonate Sr3CO5
is significant for comprehending the carbon cycle and storage mechanisms within the Earth's …

In the present work, based on the density functional theory and crystal structure prediction
algorithms, we found novel structures of alkali metal orthocarbonates Li4CO4-C 2/c …