Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations
A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …
Strategies for corrole functionalization
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
Electrochemistry of corroles in nonaqueous media
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …
1980 until the present. The outline of the review is grouped according to the periodic table …
Seven clues to ligand noninnocence: the metallocorrole paradigm
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
X-ray absorption spectroscopy as a probe of ligand noninnocence in metallocorroles: the case of copper corroles
The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Cobalt-and rhodium-corrole-triphenylphosphine complexes revisited: The question of a noninnocent corrole
A reinvestigation of cobalt–corrole–triphenylphosphine complexes has yielded an
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
Electronic structure of cobalt–corrole–pyridine complexes: noninnocent five-coordinate Co (II) corrole–radical states
Two sets of complexes of Co–triarylcorrole–bispyridine complexes, Co [T p XPC](py) 2 and
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …
Ligand Noninnocence in Iron Corroles: Insights from Optical and X‐ray Absorption Spectroscopies and Electrochemical Redox Potentials
Two new series of iron meso‐tris (para‐X‐phenyl) corrole (TpXPC) complexes, Fe [TpXPC]
Ph and Fe [TpXPC] Tol, in which X= CF3, H, Me, and OMe, and Tol= p‐methylphenyl (p …
Ph and Fe [TpXPC] Tol, in which X= CF3, H, Me, and OMe, and Tol= p‐methylphenyl (p …
A DMRG/CASPT2 investigation of metallocorroles: quantifying ligand noninnocence in archetypal 3d and 4d element derivatives
Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …
theory have been used to quantitatively compare the degree of ligand noninnocence …
Synthesis and the Effect of Anions on the Spectroscopy and Electrochemistry of Mono (dimethyl sulfoxide)-Ligated Cobalt Corroles
WR Osterloh, V Quesneau, N Desbois… - Inorganic …, 2019 - ACS Publications
A new series of cobalt A3-triarylcorroles were synthesized and the compounds examined as
to their electrochemical and spectroscopic properties in CH2Cl2 or dimethyl sulfoxide …
to their electrochemical and spectroscopic properties in CH2Cl2 or dimethyl sulfoxide …