Asymmetric polymerization

Y Okamoto, T Nakano - Chemical reviews, 1994 - ACS Publications
The synthesis and application of optically active polymers are topics currently attracting
much attention. This may arise mainly from their chiral structure which is common to …

Asymmetric kinetic resolution polymerization

G Xu, Q Mahmood, C Lv, R Yang, L Zhou… - Coordination Chemistry …, 2020 - Elsevier
Synthetic chiral polymers play an increasing and prominent role in the field of material
science due to special properties different from traditional polymer materials. One distinctive …

Functionalization of montmorillonite by methyl methacrylate polymers containing side-chain ammonium cations

L Biasci, M Aglietto, G Ruggeri, F Ciardelli - Polymer, 1994 - Elsevier
Non-extractable poly (methyl methacrylate)(PMMA)-montmorillonite adducts were prepared
by two distinct processes:(a) In the first method, free-radical copolymerization of MMA with …

Chromatographic resolution of racemates on dissymmetric sorbents

SV Rogozhin, VA Davankov - Russian Chemical Reviews, 1968 - iopscience.iop.org
The review discusses the use of natural sorbents (proteins, carbohydrates, and optically
active quartz) and also artificial dissymmetric sorbents (based on silica gel and activated …

Enantiomerically Pure Titanium Complexes Containing an [OSSO]‐Type Bis (phenolate) Ligand: Synthesis, Structure, and Formation of Optically Active Oligostyrenes

GJM Meppelder, K Beckerle… - Chemistry–An Asian …, 2008 - Wiley Online Library
Abstract Chiral 1, 2‐trans‐dithiocyclohexanediyl‐bridged bis (phenols) of the type [2, 2′‐
{HOC6H2‐6‐R1‐4‐R2} 2S2C6H10]([OSSO] H2, R1= tBu, iPr, H; R2= tBu, iPr, Me) could be …

Direct resolution of enantiomers in column liquid chromatography

R Audebert - Journal of Liquid Chromatography, 1979 - Taylor & Francis
Important progress has been performed during the ten past years, in the direct resolution
(without derivatization) of enantiomers by column liquid chromatography. Generally chiral …

Optically active vinyl polymers. XIV. Stereoselective and stereoelective polymerization of racemic α‐olefins

P Pino, F Ciardelli, G Montagnoli - Journal of Polymer Science …, 1967 - Wiley Online Library
Abstract Polymers of racemic 4‐methyl‐1‐hexene, 3‐methyl‐1‐pentene, and 3, 7‐dimethyl‐
1‐octene have been separated in fractions having optical activity of opposite sign by …

Stereochemical aspects of the copolymerization of asymmetric α-olefins by stereospecific catalysts

F Ciardelli, C Carlini, G Montagnoli - Macromolecules, 1969 - ACS Publications
ABSTRACT; Racemic 3, 7-dimethyl-1-octene and 3-methyl-1-pentene havebeen
copolymerized, respectively, with (S)-3-methyl-1-pentene and (R)-3.7-dimethyl-1-octene in …

Helical configuration of poly(tert‐butyliminomethylene). Complete resolution and maximum optical rotation

AJM Van Beijnen, RJM Nolte… - Recueil des Travaux …, 1980 - Wiley Online Library
By repeated chromatography over optically active poly (sec‐butyliminomethylene) on glass
beads complete resolution of poly (tert‐butyliminomethylene) was obtained. The specific …

Stereospecific polymerization of asymmetric α‐olefins having different optical purity

F Ciardelli, G Montagnoli, D Pini… - Die …, 1971 - Wiley Online Library
The polymerization of racemic and optically active α‐olefins having optical purity from 10 to
95% has been investigated by several ZIEGLER‐NATTA catalysts. Especially in the case of …