Separation of trivalent actinides and lanthanides using various 'N','S'and mixed 'N, O'donor ligands: a review

A Bhattacharyya, PK Mohapatra - Radiochimica Acta, 2019 - degruyter.com
Separation of trivalent actinide (An) and lanthanide (Ln) elements is one of the burning
topics in the back end of the nuclear fuel cycle due to the similarity in their chemical …

Optical spectroscopy as a tool for studying the solution chemistry of neodymium (III)

PR Nawrocki, TJ Sørensen - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
In nature, the elements of the inorganic part of the periodic table are found in three forms:
metals, ions in salts & minerals, and ions in solution. The ions may be coordinated to simple …

Hydrophilic sulfonated 2, 9-diamide-1, 10-phenanthroline endowed with a highly effective ligand for separation of americium (III) from europium (III): extraction …

P Ren, P Huang, X Yang, Y Zou, W Tao… - Inorganic …, 2020 - ACS Publications
The design and development of a water-soluble heterocyclic ligand are believed to be an
alternative way for improving the separation efficiency of actinides from lanthanides. Herein …

Strong periodic tendency of trivalent lanthanides coordinated with a phenanthroline-based ligand: cascade countercurrent extraction, spectroscopy, and …

XF Yang, P Ren, Q Yang, JS Geng, JY Zhang… - Inorganic …, 2021 - ACS Publications
Phenanthroline-diamide ligands have been reported in the selective separation of actinides
over Eu (III); on the contrary, relevant basic coordination chemistry studies are still limited …

[HTML][HTML] Recent advances in the development of the btp motif: A versatile terdentate coordination ligand for applications in supramolecular self-assembly, cation and …

AF Henwood, IN Hegarty, EP McCarney, JI Lovitt… - Coordination Chemistry …, 2021 - Elsevier
Abstract The btp [2, 6-bis (1, 2, 3-triazol-4-yl) pyridine] ligand is a terdentate ligand that,
analogously to many other terdentate ligands such as 2, 2′; 6, 2 ″-terpyridine (terpy), has …

Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups

L Götzke, G Schaper, J März, P Kaden… - Coordination Chemistry …, 2019 - Elsevier
Over recent decades there has been a great deal of interest and associated research into
aspects of the f-block (lanthanide and actinide) metal chemistry of naturally-occurring …

Lipophilic phenanthroline diamide ligands in 1-octanol for separation of Am (III) from Eu (III)

XF Yang, Y Liu, WQ Tao, S Wang, P Ren… - Journal of …, 2022 - Elsevier
Although phenanthroline diamide (DAPhen) ligands have recently shown vast opportunity in
group separation of actinides, the commonly used diluents in research, such as …

Structure and Characterization of an Americium Bis(O,O'-diethyl)dithiophosphate Complex

RDM Greer, C Celis-Barros, JM Sperling… - Inorganic …, 2020 - ACS Publications
A facile synthesis of an americium complex with a sulfur-donor ligand has been developed,
allowing characterization of americium bonding from multiple perspectives via several …

Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review

C Ebenezer, RV Solomon - Comments on Inorganic Chemistry, 2024 - Taylor & Francis
The development of density functional theory (DFT) has significantly enhanced the use of
computational chemistry as a tool in the design and development of ligands for the …

Amino Acid Decorated Phenanthroline Diimide as Sustainable Hydrophilic Am (III) Masking Agent with High Acid Resistance

B Li, L Wang, Y Kang, H Cao, Y Liu, Q He, Z Li, X Tang… - JACS Au, 2024 - ACS Publications
Hydrophilic actinide masking agents are believed to be efficient alternatives to circumvent
the extensive hazardous organic solvents/diluents typically employed in the liquid–liquid …