Transition metal based catalysts in the aerobic oxidation of alcohols

C Parmeggiani, F Cardona - Green Chemistry, 2012 - pubs.rsc.org
The oxidation of alcohols to the corresponding carbonyl compounds is a pivotal reaction in
organic synthesis. However, traditional oxidants are often toxic and release considerable …

Innovation of hydrocarbon oxidation with molecular oxygen and related reactions

Y Ishii, S Sakaguchi, T Iwahama - Advanced Synthesis & …, 2001 - Wiley Online Library
An innovation of the aerobic oxidation of hydrocarbons through catalytic carbon radical
generation under mild conditions was achieved by using N‐hydroxyphthalimide (NHPI) as a …

Scope, kinetics, and mechanistic aspects of aerobic oxidations catalyzed by ruthenium supported on alumina

K Yamaguchi, N Mizuno - Chemistry–A European Journal, 2003 - Wiley Online Library
Abstract The Ru/Al2O3 catalyst was prepared by modification of the preparation of Ru (OH)
3⋅ n H2O. The present Ru/Al2O3 catalyst has high catalytic activities for the oxidations of …

Gold-catalyzed synthesis of benzil derivatives and α-keto imides via oxidation of alkynes

CF Xu, M Xu, YX Jia, CY Li - Organic Letters, 2011 - ACS Publications
An efficient process based on the gold-catalyzed redox reaction has been developed to
oxidize 1, 2-diarylacetylene or ynamide to 1, 2-diaryldiketone or α-keto imide respectively …

Divergent Synthetic Approach to Grayanane Diterpenoids

A Zhu, Y Lyu, Q Xia, Y Wu, D Tang, C He… - Journal of the …, 2023 - ACS Publications
The total syntheses of nine grayanane diterpenoids, namely, GTX-II (1), GTX-III (2),
rhodojaponin III (3), GTX-XV (4), principinol D (5), iso-GTX-II (6), 1, 5-seco-GTX-Δ1, 10-ene …

Novel vanadium-catalyzed oxidation of alcohols to aldehydes and ketones under atmospheric oxygen

S Velusamy, T Punniyamurthy - Organic letters, 2004 - ACS Publications
Oxidation of alcohols to aldehydes and ketones has been studied in high yields using
atmospheric oxygen and a catalytic amount of V2O5 in toluene under heating (ca. 100° C) …

Pd (II)− Hydrotalcite-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones Using Atmospheric Pressure of Air

N Kakiuchi, Y Maeda, T Nishimura… - The Journal of Organic …, 2001 - ACS Publications
A heterogenized Pd catalyst, Pd (II)− hydrotalcite (palladium (II) acetate− pyridine complex
supported by hydrotalcite) catalyzes the aerobic oxidation in toluene of a variety of primary …

Copper(II)-Catalyzed Aerobic Oxidation of Primary Alcohols to Aldehydes in Ionic Liquid [bmpy]PF6

N Jiang, AJ Ragauskas - Organic Letters, 2005 - ACS Publications
A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the
three-component system acetamido-TEMPO/Cu (ClO4) 2/DMAP in the ionic liquid [bmpy] …

Oxovanadium complex-catalyzed aerobic oxidation of propargylic alcohols

Y Maeda, N Kakiuchi, S Matsumura… - The Journal of …, 2002 - ACS Publications
A catalytic system consisting of vanadium oxyacetylacetonate [VO (acac) 2] and 3 Å
molecular sieves (MS3A) in acetonitrile works effectively for the aerobic oxidation of …

Vanadium-catalyzed asymmetric oxidation of α-hydroxy esters using molecular oxygen as stoichiometric oxidant

AT Radosevich, C Musich, FD Toste - Journal of the American …, 2005 - ACS Publications
A vanadium-catalyzed method for the oxidative kinetic resolution of α-hydroxyesters, using
oxygen as the terminal oxidant, is described. The catalyst is generated in situ from vanadium …