Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …

Magnetic anisotropies in paramagnetic polynuclear metal complexes

M Nakano, H Oshio - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of the magnetic properties of highly anisotropic paramagnetic molecules is an
area of intense current research interest. Of these, single-molecule magnets (SMMs) and …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Cyanide single-molecule magnets exhibiting solvent dependent reversible “on” and “off” exchange bias behavior

D Pinkowicz, HI Southerland, C Avendaño… - Journal of the …, 2015 - ACS Publications
The syntheses, structures, and magnetic properties of four new complex salts,(PPN){[MnIII
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …

Enhanced Ion Anisotropy by Nonconventional Coordination Geometry: Single-Chain Magnet Behavior for a [{FeIIL}2{NbIV(CN)8}] Helical Chain Compound Designed with …

TS Venkatakrishnan, S Sahoo, N Bréfuel… - Journal of the …, 2010 - ACS Publications
Nonconventional heptacoordination in combination with efficient magnetic exchange
coupling is shown to yield a 1-D heteronuclear {FeIINbIV} compound with remarkable …

Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet

MA Sørensen, UB Hansen, M Perfetti… - Nature …, 2018 - nature.com
Total control over the electronic spin relaxation in molecular nanomagnets is the ultimate
goal in the design of new molecules with evermore realizable applications in spin-based …

Cyano‐Bridged MnIIIMIII Single‐Chain Magnets with MIII=CoIII, FeIII, MnIII, and CrIII

H Miyasaka, T Madanbashi, A Saitoh… - … A European Journal, 2012 - Wiley Online Library
A series of isostructural cyano‐bridged MnIII (hs)–MIII (ls) alternating chains,[MnIII (5‐
TMAMsalen) MIII (CN) 6]⋅ 4H2O (5‐TMAMsalen2−= N, N′‐ethylenebis (5 …

Beyond the spin model: exchange coupling in molecular magnets with unquenched orbital angular momenta

A Palii, B Tsukerblat, S Klokishner… - Chemical Society …, 2011 - pubs.rsc.org
In this critical review we review the problem of exchange interactions in polynuclear metal
complexes involving orbitally degenerate metal ions. The key feature of these systems is …

Hydrogen-bond directed cyanide-bridged molecular magnets derived from polycyanidemetalates and Schiff base manganese (III) compounds: synthesis, structures …

D Zhang, H Wang, Y Chen, ZH Ni, L Tian… - Inorganic …, 2009 - ACS Publications
A series of six new cyanide-bridged heterometallic complexes including two tetranuclear T-
like FeIIIMnIII3 compounds,{[Mn (L1)(H2O)] 3 [Fe (CN) 5 (1-CH3im)]} ClO4· 1.5 H2O (1) and …

Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes

AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …