Carbon–carbon bond forming reactions via photogenerated intermediates

D Ravelli, S Protti, M Fagnoni - Chemical reviews, 2016 - ACS Publications
The present review offers an overview of the current approaches for the photochemical and
photocatalytic generation of reactive intermediates and their application in the formation of …

The chemistry of heterocycles in the 21st century

VN Charushin, EV Verbitskiy, ON Chupakhin… - Uspekhi Khimii, 2024 - mathnet.ru
The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

1,n‐Hydrogen‐Atom Transfer (HAT) Reactions in Which n≠5: An Updated Inventory

M Nechab, S Mondal… - Chemistry–A European …, 2014 - Wiley Online Library
Hydrogen‐atom transfer (HAT) counts amongst the most widely investigated routes to
carbon‐centered radicals. Intramolecular processes involving 1, 5‐HAT are widespread to …

The Baldwin rules: revised and extended

K Gilmore, RK Mohamed… - Wiley Interdisciplinary …, 2016 - Wiley Online Library
The Baldwin rules constitute one of the clearest examples of the success which can be
obtained through the application of stereoelectronic concepts to reaction design. With …

Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones

HE Ho, A Pagano, JA Rossi-Ashton, JR Donald… - Chemical …, 2020 - pubs.rsc.org
Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can
undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols …

Photoredox Cyclization of N-Arylacrylamides for Synthesis of Dihydroquinolinones

Z Liu, S Zhong, X Ji, GJ Deng, H Huang - Organic Letters, 2021 - ACS Publications
Metal-and additive-free photoredox cyclization of N-arylacrylamides is herein reported that
provides a concise access to the formation of dihydroquinolinones. In this protocol …

Finding the right path: Baldwin “Rules for Ring Closure” and stereoelectronic control of cyclizations

IV Alabugin, K Gilmore - Chemical Communications, 2013 - pubs.rsc.org
Truly important scientific breakthroughs often come from catching the glimpses of order in
chaos and distilling a large body of disjointed data into a clear set of simple concepts. Even …

Orbital hybridization: a key electronic factor in control of structure and reactivity

IV Alabugin, S Bresch… - Journal of Physical …, 2015 - Wiley Online Library
This review outlines fundamental factors responsible for hybridization trends in organic and
main group compounds. Hybridization is a classic chemical concept that transcends …

Local electronic and chemical structure of oligo-acetylene derivatives formed through radical cyclizations at a surface

A Riss, S Wickenburg, P Gorman, LZ Tan, HZ Tsai… - Nano …, 2014 - ACS Publications
Semiconducting π-conjugated polymers have attracted significant interest for applications in
light-emitting diodes, field-effect transistors, photovoltaics, and nonlinear optoelectronic …

Redox of dual-radical intermediates in a methylene-linked covalent triazine framework for high-performance lithium-ion batteries

Z Wang, S Gu, L Cao, L Kong, Z Wang… - … Applied Materials & …, 2020 - ACS Publications
Covalent triazine frameworks (CTFs) are promising electrodes for rechargeable batteries
due to their adjustable structures, rich redox sites, and tunable porosity. However, the CTFs …