Polymerization of polar monomers mediated by main-group Lewis acid–base pairs

M Hong, J Chen, EYX Chen - Chemical reviews, 2018 - ACS Publications
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

Recyclable and (Bio) degradable polyesters in a circular plastics economy

C Shi, EC Quinn, WT Diment, EYX Chen - Chemical Reviews, 2024 - ACS Publications
Polyesters carrying polar main-chain ester linkages exhibit distinct material properties for
diverse applications and thus play an important role in today's plastics economy. It is …

4D printing of resorbable complex shape-memory poly (propylene fumarate) star scaffolds

G Le Fer, ML Becker - ACS applied materials & interfaces, 2020 - ACS Publications
3D/4D printing is enabling transformative advances in device manufacturing and medicine
but remains limited by the lack of printable resorbable materials with advanced properties …

Poly (propylene fumarate)-based materials: Synthesis, functionalization, properties, device fabrication and biomedical applications

Z Cai, Y Wan, ML Becker, YZ Long, D Dean - Biomaterials, 2019 - Elsevier
Abstract Poly (propylene fumarate)(PPF) is a biodegradable polymer that has been
investigated extensively over the last three decades. It has led many scientists to synthesize …

Simple and Efficient Zinc Catalysts for Synthesis and Chemical Degradation of Polyesters

F Santulli, D Pappalardo, M Lamberti… - ACS Sustainable …, 2023 - ACS Publications
A series of zinc complexes supported by tridentate imino-phenolate ligands with different
substituents on the phenolate ring and bearing a pyridyl ring as an additional coordinative …

Dual catalysis for selective ring-opening polymerization of lactones: Evolution toward simplicity

S Naumann, PBV Scholten, JA Wilson… - Journal of the American …, 2015 - ACS Publications
Much work has been directed to the design of complex single-site catalysts for ring-opening
polymerization (ROP) to enhance both activity and selectivity. More simply, however …

N-Heterocyclic Olefin-Based (Co)polymerization of a Challenging Monomer: Homopolymerization of ω-Pentadecalactone and Its Copolymers with γ-Butyrolactone, δ …

P Walther, S Naumann - Macromolecules, 2017 - ACS Publications
A setup consisting of N-heterocylic olefins (NHOs) and several simple Lewis acids (such as
MgCl2 or LiCl) was employed to homopolymerize ω-pentadecalactone (PDL) and to …

Magnesium catalyzed polymerization of end functionalized poly (propylene maleate) and poly (propylene fumarate) for 3D printing of bioactive scaffolds

JA Wilson, D Luong, AP Kleinfehn… - Journal of the …, 2018 - ACS Publications
The ring-opening copolymerization of maleic anhydride and propylene oxide, using a
functionalized primary alcohol initiator and magnesium 2, 6-di-tert-butyl phenoxide as a …

Coordination ring-opening polymerization of cyclic esters: A critical overview of DFT modeling and visualization of the reaction mechanisms

I Nifant'ev, P Ivchenko - Molecules, 2019 - mdpi.com
Ring-opening polymerization (ROP) of cyclic esters (lactones, lactides, cyclic carbonates
and phosphates) is an effective tool to synthesize biocompatible and biodegradable …