Photoremovable protecting groups in chemistry and biology: reaction mechanisms and efficacy

P Klán, T Solomek, CG Bochet, A Blanc… - Chemical …, 2013 - ACS Publications
Photoremovable Protecting Groups in Chemistry and Biology: Reaction Mechanisms and
Efficacy | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

Searching for improved photoreleasing abilities of organic molecules

T Solomek, J Wirz, P Klan - Accounts of chemical research, 2015 - ACS Publications
Conspectus Photoremovable protecting groups (PPGs) are chemical auxiliaries that provide
spatial and temporal control over the release of various molecules: bioagents …

Visible‐light‐induced photoreductive generation of radicals from epoxides and aziridines

MH Larraufie, R Pellet, L Fensterbank, JP Goddard… - Angewandte …, 2011 - infona.pl
Gefangen! Epoxide und Aziridine mit Arylketonsubstituent können effizient mit
Photoredoxkatalysatoren reduziert werden, die mit sichtbarem Licht arbeiten. Die erzeugten …

Strategic Application and Transformation of ortho-Disubstituted Phenyl and Cyclopropyl Ketones To Expand the Scope of Hydrogen Borrowing Catalysis

JR Frost, CB Cheong, WM Akhtar… - Journal of the …, 2015 - ACS Publications
The application of an iridium-catalyzed hydrogen borrowing process to enable the formation
of α-branched ketones with higher alcohols is described. In order to facilitate this reaction …

Photochemistry of S-Phenacyl Xanthates

A Tazhe Veetil, T Solomek, BP Ngoy… - The Journal of …, 2011 - ACS Publications
Various synthetically readily accessible S-phenacyl xanthates are shown to undergo
photoinitiated homolytic scission of the C–S bond in the primary step. The resultant …

The power of solvent in altering the course of photorearrangements

P Sebej, BH Lim, BS Park, RS Givens, P Klán - Organic letters, 2011 - ACS Publications
A clean bifurcation between two important photochemical reactions through competition of a
triplet state Type II H-abstraction reaction with a photo-Favorskii rearrangement for (o/p) …

Photoenolization and its Applications

P Klán, J Wirz, AD Gudmundsdottir - CRC Handbook of Organic …, 2019 - taylorfrancis.com
Photoenolization reactions have been comprehensively reviewed in 1976 by Sammes
(Sammes 1976) and, to some extent, in several more recent reviews and book chapters …

FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes

DH Dethe, GM Murhade, S Ghosh - The Journal of Organic …, 2015 - ACS Publications
An intramolecular FeCl3-catalyzed Michael addition reaction of styrene, a poor nucleophile,
onto α, β-unsaturated ketones was developed for the synthesis of highly substituted indene …

Facile synthesis of dihydrochalcones via the AlCl3-promoted tandem Friedel–Crafts acylation and alkylation of arenes with 2-alkenoyl chlorides

Y Zhou, X Li, S Hou, J Xu - Journal of Molecular Catalysis A: Chemical, 2012 - Elsevier
Tandem Friedel–Crafts acylation and alkylation of arenes with 2-alkenoyl chlorides were
investigated under the catalysis of Lewis acids. The cascade reaction affords …

Photochemical studies on aromatic γ, δ-epoxy ketones: efficient synthesis of benzocyclobutanones and indanones

Y Shao, C Yang, W Gui, Y Liu, W Xia - Chemical Communications, 2012 - pubs.rsc.org
Irradiation of terminal aromatic γ, δ-epoxy ketones with a 450 W UV lamp led to Norrish type
II cyclization/semi-pinacol rearrangement cascade reaction which formed the …