While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Virtually all organosulfur compounds react with Fe (0) carbonyls to give the title complexes.
These reactions are reviewed in light of major advances over the past few decades, spurred …

This article reviews published literature on the electrochemical reduction and oxidation of
complexes containing the Fe2S2 core characteristic of the active site of [FeFe] …

The cobalt analogue of a highly active nickel electrocatalyst for hydrogen production has
been synthesized and characterized as [Co (PPh2NPh2) 2 (CH3CN)](BF4) 2. In the …

As the [2Fe] H subsite models of [FeFe]-hydrogenases, a series of PNP-chelated and-
bridged diiron dithiolate complexes 1a–f and 2a–f together with the three related …

Reactions of Fe2 (CO) 6 (μ-pdt)(pdt= SCH2CH2CH2S) with aminodiphosphines Ph2PN (R)
PPh2 (R= allyl, iPr, iBu, p-tolyl, H) have been carried out under different conditions. At room …

Hydrogenase biomimetics: Fe 2 (CO) 4 (μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
both a proton-reduction and hydrogen oxidation cata ... - Chemical Communications (RSC …

Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …

No CO‐operation: Two single‐site ruthenium complexes, based on a tetradentate ligand,
despite structural similarities, display a remarkable difference in their catalytic and chemical …

[FeFe]-Ase biomimics containing a redox-active ferrocenyl diphosphine have been prepared
and their ability to reduce protons and oxidise H2 studied, including 1, 1′-bis …