We report an iron‐catalyzed decarboxylative C (sp3)− O bond‐forming reaction under mild,
base‐free conditions with visible light irradiation. The transformation uses readily available …

Organic transformations associated with metal mediated electron transfer processes are
really worthy of remarkable considering the biological importance of redox active metal ions …

[FeIII (OH)(tpena)]+(tpena–= N, N, N′-tris (2-pyridylmethyl) ethylenediamine-N′-acetate)
catalytically activates H2O2 with the concomitant formation of the active oxidants [FeIV …

Precise delivery of a proton plays a key role in O2 activation at iron oxygenases, enabling
the crucial O− O cleavage step that generates the oxidizing high‐valent metal–oxo species …

Herein, by using state-of-the-art mass spectrometry, we demonstrated experimentally that
the bimetallic copper-vanadium oxide cluster anions CuVO3, 4–can catalyze the reduction …

This computational study revises and reformulates the mechanism for the cross-coupling
reaction between chlorobenzene and tetrahydrofuran catalyzed by a Ni complex with the …

Photo‐mineralization of microplastics under mild conditions has emerged as a promising
solution to plastic waste disposal. However, the inadequate contact between oxygen, water …

By using state-of-the-art mass spectrometry and guided by the newly discovered single-
electron mechanism (SEM; eg, Ti3++ 2NO→ Ti4+–O•–+ N2O), we determined …

Dinuclear Cu2 (II, II)-cores stabilized by the N3O donorset of HL1=(2-{[[di (2-pyridyl)
methyl](methyl) amino] methyl} phenol), HL2= 2-({[di (2-pyridyl) methyl] amino} methyl) …

Aqueous solutions of the iron (III) complex of N, N, N′-tris (2-pyridylmethyl)
ethylenediamine-N′-acetate (tpena) react with hypochlorite (ClO–) to produce the reactive …