Chirality is a fundamental property which plays a major role in chemistry, physics, biological
systems and materials science. Chiroptical artificial molecular motors (AMMs) are a class of …

Bisimine derivatives of salicylaldehyde with chiral diamines (salens) are privileged ligands
in asymmetric organometallic catalysis, which can be used in cooperation with …

Figure 73: The proposed catalyst/substrate interaction shown in Figure 73 corresponds to
the related sulfoxidation catalyzed by chiral phosphoric acid PA 5 (ref 133). Please note that …

Vibrational circular dichroism (VCD) spectroscopy is one of the most powerful techniques for
the determination of absolute configurations (AC), as it does not require any specific UV/vis …

Vibrational circular dichroism (VCD) spectroscopy has become an important part of the
(stereo-) chemists' toolbox as a reliable method for the determination of absolute …

We demonstrate that molecular vibrations with originally low or zero intensity in a vibrational
circular dichroism (VCD) spectrum attain chirality in molecular crystals by coordinated …

By virtue of noninvasive regulations by light, photocontrolled polymerizations have attracted
considerable attention for the precision synthesis of macromolecules. However, a cationic …

A main focus of physical chemistry and related disciplines targets a detailed and
fundamental characterization of intermolecular interactions. Interests are manifold and range …

Stable carbocations such as tritylium ions have been widely explored as organic Lewis acid
catalysts and reagents in organic synthesis. However, achieving asymmetric carbocation …

We report the first fully ab initio calculation of dynamical vibrational circular dichroism
spectra in the liquid phase using nuclear velocity perturbation theory (NVPT) derived …