Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

Quantum mechanical studies of large metal, metal oxide, and metal chalcogenide nanoparticles and clusters

A Fernando, KLDM Weerawardene… - Chemical …, 2015 - ACS Publications
Metal, metal oxide, and metal chalcogenide materials have a wide variety of applications.
For example, many metal clusters and nanoparticles are used as catalysts for reactions …

On the ligand's role in the fluorescence of gold nanoclusters

Z Wu, R Jin - Nano letters, 2010 - ACS Publications
The fluorescence of metal nanoparticles (such as gold and silver) has long been an
intriguing topic and has drawn considerable research interest. However, the origin of …

Quantum sized, thiolate-protected gold nanoclusters

R Jin - Nanoscale, 2010 - pubs.rsc.org
The scientific study of gold nanoparticles (typically 1–100 nm) has spanned more than 150
years since Faraday's time and will apparently last longer. This review will focus on a special …

Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties

M Zhu, CM Aikens, FJ Hollander… - Journal of the …, 2008 - ACS Publications
The total structure determination of thiol-protected Au clusters has long been a major issue
in cluster research. Herein, we report an unusual single crystal structure of a 25-gold-atom …

A unified view of ligand-protected gold clusters as superatom complexes

M Walter, J Akola, O Lopez-Acevedo… - Proceedings of the …, 2008 - National Acad Sciences
Synthesis, characterization, and functionalization of self-assembled, ligand-stabilized gold
nanoparticles are long-standing issues in the chemistry of nanomaterials. Factors driving the …

Atomic and electronic structure of gold clusters: understanding flakes, cages and superatoms from simple concepts

H Häkkinen - Chemical Society Reviews, 2008 - pubs.rsc.org
Atomic structure and electronic structure are intimately interrelated properties of
nanoclusters and nanoparticles, defining their stability, electronic, optical and chemical …

Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au11(PPh3)7Cl3 and [Au11(PPh3)8Cl2]Cl, Exhibit Distinct Ligand Exchange Pathways with …

LC McKenzie, TO Zaikova… - Journal of the American …, 2014 - ACS Publications
Ligand exchange is frequently used to introduce new functional groups on the surface of
inorganic nanoparticles or clusters while preserving the core size. For one of the smallest …