Supramolecular assembly of a 4-(1-naphthylvinyl) pyridine-appended Zn (ii) coordination compound for the turn-on fluorescence sensing of trivalent metal ions (Fe 3+ …
Supramolecular systems are formed by the assembly of two or more molecules to achieve
different or better functions with respect to those of the individual molecules. Secondary …
different or better functions with respect to those of the individual molecules. Secondary …
Interconversion and reactivity of manganese silyl, silylene, and silene complexes
JS Price, DJH Emslie - Chemical Science, 2019 - pubs.rsc.org
Manganese disilyl hydride complexes [(dmpe) 2MnH (SiH2R) 2](4Ph: R= Ph, 4Bu: R= nBu)
reacted with ethylene to form silene hydride complexes [(dmpe) 2MnH (RHSiCHMe)](6Ph …
reacted with ethylene to form silene hydride complexes [(dmpe) 2MnH (RHSiCHMe)](6Ph …
NHC-Stabilized Silyl-Substituted Chlorosilylene
The first N-heterocyclic carbene (NHC) stabilized silyl-substituted chlorosilylene (1) was
isolated via selective dehydrochlorination by NHC from silyl-based Si (IV) precursor t …
isolated via selective dehydrochlorination by NHC from silyl-based Si (IV) precursor t …
NHC-stabilized silyl-substituted silyliumylidene ions
P Frisch, S Inoue - Dalton Transactions, 2019 - pubs.rsc.org
The first silyl-substituted silyliumylidene ions are reported. The scope of a previously
described convenient one-step procedure for the preparation of N-heterocyclic carbene …
described convenient one-step procedure for the preparation of N-heterocyclic carbene …
Single‐Source Precursors for the Chemical Vapor Deposition of Iron Germanides
Binary iron‐germanium phases are promising materials in magnetoelectric, spintronic or
data storage applications due to their unique magnetic properties. Previous protocols for …
data storage applications due to their unique magnetic properties. Previous protocols for …
An Air‐Stable Heterobimetallic Si2M2 Tetrahedral Cluster
Air‐and moisture‐stable heterobimetallic tetrahedral clusters [Cp (CO) 2MSiR] 2 (M= Mo or
W; R= SitBu3) were isolated from the reaction of N‐heterocyclic carbene (NHC) stabilized …
W; R= SitBu3) were isolated from the reaction of N‐heterocyclic carbene (NHC) stabilized …
Reactivity of an NHC-Coordinated Trisilacyclopropylidene with Transition Metal Carbonyl Compounds
The reaction of the NHC-coordinated trisilacyclopropylidene F with freshly prepared W (CO)
6–n (thf) n (n= 1, 2) yielded in addition to the targeted tungsten pentacarbonyl complex 1 the …
6–n (thf) n (n= 1, 2) yielded in addition to the targeted tungsten pentacarbonyl complex 1 the …
X‐ray Crystallography of Organogermanium Compounds
C Hemmert, H Gornitzka - … Compounds: Theory, Experiment …, 2023 - Wiley Online Library
X‐ray structural analysis plays an essential role in organogermanium chemistry. Some
structural features of germanium‐containing compounds are summarized in this chapter …
structural features of germanium‐containing compounds are summarized in this chapter …
Influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene
We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a
diphosphene TerPPTer (1; Ter= 2, 6-Mes2C6H3; Mes= 2, 4, 6-Me3C6H2), a phosphorus …
diphosphene TerPPTer (1; Ter= 2, 6-Mes2C6H3; Mes= 2, 4, 6-Me3C6H2), a phosphorus …
An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene
T Lainer, D Dange, M Pillinger, RC Fischer… - …, 2022 - Wiley Online Library
A convenient metal‐free approach towards an N‐heterocyclic carbene (NHC)‐coordinated
disilene 2 is described. Compound 2, featuring the disilene incorporated in cyclopolysilane …
disilene 2 is described. Compound 2, featuring the disilene incorporated in cyclopolysilane …