Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Activation and conversion of alkanes in the confined space of zeolite-type materials

P Del Campo, C Martínez, A Corma - Chemical Society Reviews, 2021 - pubs.rsc.org
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Aromatics production via methanol-mediated transformation routes

T Li, T Shoinkhorova, J Gascon, J Ruiz-Martinez - ACS Catalysis, 2021 - ACS Publications
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …

Advances in theory and their application within the field of zeolite chemistry

V Van Speybroeck, K Hemelsoet, L Joos… - Chemical Society …, 2015 - pubs.rsc.org
Zeolites are versatile and fascinating materials which are vital for a wide range of industries,
due to their unique structural and chemical properties, which are the basis of applications in …

Lewis–Brønsted acid pairs in Ga/H-ZSM-5 to catalyze dehydrogenation of light alkanes

MW Schreiber, CP Plaisance… - Journal of the …, 2018 - ACS Publications
The active sites for propane dehydrogenation in Ga/H-ZSM-5 with moderate concentrations
of tetrahedral aluminum in the lattice were identified to be Lewis–Brønsted acid pairs. With …

Engineering zeolites for catalytic cracking to light olefins

V Blay, B Louis, R Miravalles, T Yokoi… - ACS …, 2017 - ACS Publications
Propene is a key building block for the petrochemical industry whose demand is increasing
strongly in recent years, even faster than that of ethene. The availability of propene is limited …

[图书][B] Fischer-tropsch refining

A De Klerk - 2012 - books.google.com
The Fischer-Tropsch process is gaining recognition again due to the world-wide increase in
energy needs and decrease in oil availability. The increasing interest in utilizing biomass as …

Molecular simulations of zeolites: adsorption, diffusion, and shape selectivity

B Smit, TLM Maesen - Chemical reviews, 2008 - ACS Publications
Zeolites are intriguing materials. The basic building blocks are corner sharing TO4 units,
where the T-atoms usually refer to Si, Al, or in some cases also P. These tetrahedrals can …

Size-dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts

J Zhu, ML Yang, Y Yu, YA Zhu, ZJ Sui, XG Zhou… - Acs …, 2015 - ACS Publications
Platinum cluster size has a significant influence on the activity, selectivity, and stability as
well as the reaction mechanism during propane dehydrogenation (PDH). Well-controlled …

The catalytic diversity of zeolites: confinement and solvation effects within voids of molecular dimensions

R Gounder, E Iglesia - Chemical Communications, 2013 - pubs.rsc.org
The ability of molecular sieves to control the access and egress of certain reactants and
products and to preferentially contain certain transition states while excluding others based …