The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

Catalytic generation of ambiphilic π-allyl–metal complexes and their utility in
enantioselective transformations constitutes a powerful approach for introduction of allyl …

Lycorane is a pentacyclic core presented in alkaloids isolated from the Amaryllidaceae
family of herbaceous flowering plants. Members of this class of natural products have shown …

The highly diastereo-and enantioselective title reaction of a range of cyclic imines with
various potassium allyltrifluoroborates most likely proceeds via allylrhodium (I) …

Various allylic alcohols were carboxylated in the presence of a catalytic amount of PdCl2
and PPh3 using ZnEt2 as a stoichiometric transmetalation agent under a CO2 atmosphere …

Get selective! Enantioselective allylation of ketimines derived from isatins by using chiral 1, 3‐
bis (imidazolin‐2‐yl) benzene (Phebim)–PdII complexes afforded products with good …

The direct catalytic three-component coupling of aldehydes (1), carbamates (or amines; 2),
and nontoxic allyltrimethylsilane (3) is a very effective approach to homoallylic amine …

A catalytic asymmetric conjugate allylation was successfully developed to synthesize
potential pharmacologically active 4-allyl-2-oxochroman skeletons. A dual activation …

Oxazines are an important class of compounds in oxazine ligands and medical chemistry.
Here, we describe a linear-selective allylation of imines with allyl electrophiles via cross …

The development of a catalytic asymmetric method for the direct aminoallylation of
aldehydes is described that gives high asymmetric inductions for a broad range of …