Electrochemical cascade reactions: an account of recent developments for this modern strategic tool in the arsenal of chemical synthesis

MK Yadav, S Chowdhury - Green Chemistry, 2023 - pubs.rsc.org
In view of the growing demand for synthetic molecules or materials by researchers from both
the core sciences and interdisciplinary sectors, the field of organic synthesis needs to be …

Recent advances in electrocatalytic generation of indole-derived radical cations and their applications in organic synthesis

W Zhou, X Chen, L Lu, XR Song, MJ Luo… - Chinese Chemical …, 2024 - Elsevier
Indole-derived radical cations, open-shell reactive species, display distinctive dual reactivity
due to the carbon-centered radical and more electrophilic carbocation, which frequently …

Enantioselective synthesis of saddle-shaped eight-membered lactones with inherent chirality via organocatalytic high-order annulation

SQ Shi, CC Cui, LL Xu, JP Zhang, WJ Hao… - Nature …, 2024 - nature.com
Inherently chiral medium-ring derivatives have important applications in many research
fields, such as materials science, molecular recognition, and asymmetric catalysis. However …

Rhodaelectro-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling of Indole-3-carboxylic Acids and Olefins via Weakly Coordinating Carboxyl Groups

J Zhang, W Xu, W Zhuang, X Chen… - The Journal of …, 2023 - ACS Publications
A rhodaelectro-catalyzed C2–H selectively decarboxylative alkenylation of 3-carboxy-1 H-
indoles employing electricity as the traceless terminal oxidant has been accomplished. The …

Visible-light driven acetoxylation and dioxygenation of indoles via electron donor–acceptor complexes

A Paul, A Sengupta, S Yadav - Chemical Communications, 2023 - pubs.rsc.org
A photoresponsive electron donor–acceptor (EDA) complex, formed by indole and
hypervalent iodine such as diacetoxyiodobenzene (DAIB/PIDA, etc.), was detectable …

Electrochemical Oxidation of Indoles to Access Tryptanthrins at Room Temperature

Z Guo, Y Liu, H Li, J Wu, M Xie… - Advanced Synthesis & …, 2024 - Wiley Online Library
An electrooxidative reconstruction of the indole core under ambient conditions is reported,
resulting in the construction of tryptanthrins. This electrochemical strategy simplifies …

Electro-organic synthesis of isatins and hydrazones through C–N cross-coupling and C (sp 2)–H/C (sp 3)–H functionalization

N Verma, R Tyagi, A Khanna, M Malviya… - Organic & Biomolecular …, 2023 - pubs.rsc.org
An efficient and unique approach to synthesize isatin (indole-2, 3-dione) from 2-
aminoacetophenone under electrochemical conditions supported by I2–DMSO through C–N …

A facile synthesis of phthalimides from o-phthalaldehyde and amines via tandem cyclocondensation and α-C–H oxidation by an electrochemical oxygen reduction …

N Neerathilingam, S Prabhu… - Organic & Biomolecular …, 2023 - pubs.rsc.org
Electrochemical synthesis of phthalimides from o-phthalaldehyde and amines via tandem
cyclocondensation and α-C–H oxygenation of isoindolinone was achieved. The α-C–H …

Recent Advances in The Electrochemical Functionalization of N-heterocycles

S Chowdhury, MK Yadav - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
Nitrogen-containing heterocyclic cores are of immense importance due to their high
abundance in naturally occurring or synthetic molecules having wide applications in …

Cascade Electrochemical Aerobic Oxygenation of 2-Substituted Indoles and Electrochemical [5+ 3] Annulation with Amidines: Access to Eight-Membered Benzo [1, 3 …

W Zhuang, F Xiao, Y Chen, X Zhang… - The Journal of Organic …, 2024 - ACS Publications
The cascade electrochemical C3-selective aerobic oxygenation of 2-substituted indoles and
electrochemical [5+ 3] annulation with amidines through an undivided cell galvanostatic …