The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …

The synthesis, structure, and magnetic properties of three DyIII complexes of different
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …

A molecular dysprosium (III) complex [Dy (DClQ) 3 (H2O) 2](1) was used as a building unit
for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy (III) …

We report the synthesis of [(L) DyIII (Cy3PO) 2]·[BPh4](1-Dy)(where H2L= 2, 6-
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …

Here we use a pseudoallyl ligand, N, N′-chelating amidinate (Am), together with
pentamethylcyclopentadienyl (Cp*) to give two dysprosium (III) single-molecule magnets …

In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …

With the aim to tune the magnetic anisotropies of six-coordinated Dy (III) complexes, four bis-
Schiff bases bearing different spacers and one mono-Schiff base were designed, namely bis …

The novel LnIII {Ln= Dy (1-Dy), Gd (2-Gd), and La (3-La)} benzimidazolium tricarboxylate
coordination polymers have been synthesized, and their magnetic properties have been …

Comprehensive Summary One dihydride‐bridged dimeric Dy (III) guanidinate complex,
formulated as [{(Me3Si) 2NC (NiPr) 2} 2Dy (μ‐H)] 2 (1Dy), was successfully isolated and the …

Targeted approaches for manipulating the coordination geometry of lanthanide ions are a
promising way to synthesize high-performance single-molecule magnets (SMMs), but most …