Conspectus Chemo-and stereoselective transformations of polyborylalkanes are powerful
and efficient methods to access optically active molecules with greater complexity and …

Recent years have witnessed an increase in the popularity of α-boryl organometallic
reagents as versatile nucleophiles in asymmetric synthesis. These compounds have been …

Cu-catalyzed highly stereoselective and enantiodivergent syntheses of (Z)-or (E)-β, γ-
unsaturated ketones from 1, 3-butadienyl silanes are developed. The nature of the silyl …

We report herein a Cu‐catalyzed regio‐, diastereo‐and enantioselective acylboration of 1, 3‐
butadienylboronate with acyl fluorides. Under the developed conditions, the reactions …

The development of α, α-disubstituted crotylboronate reagents is reported. Chiral Brønsted
acid-catalyzed asymmetric aldehyde addition with the developed E-crotylboron reagent …

We report herein the development of stereodivergent syntheses of enantioenriched
homoallylic alcohols using chiral nonracemic α‐CH2Bpin‐substituted crotylboronate. Chiral …

We report herein a rare example of enantiodivergent aldehyde addition with β‐alkenyl allylic
boronates via chiral Brønsted acid catalysis. 2, 6‐Di‐9‐anthracenyl‐substituted chiral …

Stereo-and enantioselective syntheses of 1, 2-oxaborinan-3-enes and δ-boryl-substituted
homoallylic alcohols are reported. We developed a practical approach to synthesize α-boryl …

The allylation of aldehydes is a fundamental transformation in synthetic organic chemistry.
Among the multitude of available reagents, allylsilanes especially have been established as …

We report the highly diastereo‐and enantioselective preparation of (E)‐δ‐boryl‐substituted
anti‐homoallylic alcohols in two steps from terminal alkynes. This method consists of a …