Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Nickel-catalyzed reductive carboxylation and amidation reactions

A Tortajada, M Borjesson, R Martin - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The ubiquity and importance of carboxylic acids and amides in peptides,
pharmaceuticals, agrochemicals, and synthetic materials has challenged chemists to design …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Photoinduced hydrocarboxylation via thiol-catalyzed delivery of formate across activated alkenes

SN Alektiar, ZK Wickens - Journal of the American Chemical …, 2021 - ACS Publications
Herein we disclose a new photochemical process to prepare carboxylic acids from formate
salts and alkenes. This redox-neutral hydrocarboxylation proceeds in high yields across …

Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation

S Monticelli, A Talbot, P Gotico, F Caillé… - Nature …, 2023 - nature.com
Harvesting sunlight to drive carbon dioxide (CO2) valorisation represents an ideal concept
to support a sustainable and carbon-neutral economy. While the photochemical reduction of …

α-Amino Acids and Peptides as Bifunctional Reagents: Carbocarboxylation of Activated Alkenes via Recycling CO2

LL Liao, GM Cao, YX Jiang, XH Jin, XL Hu… - Journal of the …, 2021 - ACS Publications
Carboxylic acids, including amino acids (AAs), have been widely used as reagents for
decarboxylative couplings. In contrast to previous decarboxylative couplings that release …

A radical approach to anionic chemistry: synthesis of ketones, alcohols, and amines

S Ni, NM Padial, C Kingston… - Journal of the …, 2019 - ACS Publications
Historically accessed through two-electron, anionic chemistry, ketones, alcohols, and
amines are of foundational importance to the practice of organic synthesis. After placing this …

Utilization of C(sp3)‐Carboxylic Acids and Their Redox‐Active Esters in Decarboxylative Carbon−Carbon Bond Formation

S Karmakar, A Silamkoti, NA Meanwell… - Advanced Synthesis …, 2021 - Wiley Online Library
Over the last several years, radical‐mediated decarboxylative cross‐coupling reactions
employing alkyl carboxylic acids have emerged as a powerful tool for the regiospecific …

Molecular editing of pyrroles via a skeletal recasting strategy

X Zhou, Q Huang, J Guo, L Dai, Y Lu - ACS Central Science, 2023 - ACS Publications
Heterocyclic scaffolds are commonly found in numerous biologically active molecules,
therapeutic agents, and agrochemicals. To probe chemical space around heterocycles …

Radical‐based synthesis and modification of amino acids

FJ Aguilar Troyano, K Merkens, K Anwar… - Angewandte Chemie …, 2021 - Wiley Online Library
Amino acids (AAs) are key structural motifs with widespread applications in organic
synthesis, biochemistry, and material sciences. Recently, with the development of milder …